Literature DB >> 26181828

Copper-Catalyzed Cross-Coupling Reaction of Allyl Boron Ester with 1°/2°/3°-Halogenated Alkanes.

Guang-Zu Wang1, Jian Jiang1, Xiao-Song Bu1, Jian-Jun Dai1, Jun Xu2, Yao Fu2, Hua-Jian Xu1.   

Abstract

The cross-coupling reaction of allyl boron ester with 1°/2°/3°-halogenated alkanes in the presence of copper has been developed for the first time, which provides a mild and efficient method for the construction of saturated C(sp(3))-C(sp(3)) bonds. This protocol shows excellent compatibility with the nonactivated primary, secondary, and even tertiary halogenated alkanes under mild conditions.

Entities:  

Year:  2015        PMID： 26181828     DOI： 10.1021/acs.orglett.5b01612

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

Review 1.  Transition metal-catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry.

Authors:  Junwon Choi; Gregory C Fu
Journal:  Science       Date:  2017-04-14       Impact factor: 47.728

2.  Stereospecific Nickel-Catalyzed Reductive Cross-Coupling of Alkyl Tosylate and Allyl Alcohol Electrophiles.

Authors:  Quentin D Tercenio; Erik J Alexanian
Journal:  Org Lett       Date:  2021-08-31       Impact factor: 6.072

3.  Divergent Elementoboration: 1,3-Haloboration versus 1,1-Carboboration of Propargyl Esters.

Authors:  Lewis C Wilkins; Yashar Soltani; James R Lawson; Ben Slater; Rebecca L Melen
Journal:  Chemistry       Date:  2018-04-27       Impact factor: 5.236

4.  Cu-catalyzed cross-coupling reactions of vinyl epoxide with organoboron compounds: access to homoallylic alcohols.

Authors:  Xiao-Yu Lu; Jin-Song Li; Jin-Yu Wang; Shi-Qun Wang; Yue-Ming Li; Yu-Jing Zhu; Ran Zhou; Wen-Jing Ma
Journal:  RSC Adv       Date:  2018-12-12       Impact factor: 4.036
  4 in total

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