Literature DB >> 26172642

Spatial distribution of thermal energy in equilibrium.

Yohai Bar-Sinai1, Eran Bouchbinder1.   

Abstract

The equipartition theorem states that in equilibrium, thermal energy is equally distributed among uncoupled degrees of freedom that appear quadratically in the system's Hamiltonian. However, for spatially coupled degrees of freedom, such as interacting particles, one may speculate that the spatial distribution of thermal energy may differ from the value predicted by equipartition, possibly quite substantially in strongly inhomogeneous or disordered systems. Here we show that for systems undergoing simple Gaussian fluctuations around an equilibrium state, the spatial distribution is universally bounded from above by 1/2k(B)T. We further show that in one-dimensional systems with short-range interactions, the thermal energy is equally partitioned even for coupled degrees of freedom in the thermodynamic limit and that in higher dimensions nontrivial spatial distributions emerge. Some implications are discussed.

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Year:  2015        PMID: 26172642     DOI: 10.1103/PhysRevE.91.060103

Source DB:  PubMed          Journal:  Phys Rev E Stat Nonlin Soft Matter Phys        ISSN: 1539-3755


  2 in total

1.  Local thermal energy as a structural indicator in glasses.

Authors:  Jacques Zylberg; Edan Lerner; Yohai Bar-Sinai; Eran Bouchbinder
Journal:  Proc Natl Acad Sci U S A       Date:  2017-06-27       Impact factor: 11.205

2.  Thermal fracture kinetics of heterogeneous semiflexible polymers.

Authors:  Alexander M Lorenzo; Enrique M De La Cruz; Elena F Koslover
Journal:  Soft Matter       Date:  2020-02-26       Impact factor: 3.679

  2 in total

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