Literature DB >> 26166313

Glass formation via structural fragmentation of a 2D coordination network.

D Umeyama1, N P Funnell, M J Cliffe, J A Hill, A L Goodwin, Y Hijikata, T Itakura, T Okubo, S Horike, S Kitagawa.   

Abstract

The structure of a glass obtained by the melt quenching of a two-dimensional (2D) coordination network was examined. X-ray analyses disclosed a 2D-to-0D structural transformation before and after glass formation. The mechanism is unique to coordination compounds, as it is characterized by labile and flexible coordination bonds.

Mesh:

Year:  2015        PMID: 26166313     DOI: 10.1039/c5cc04626b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Ultrahigh-field 67Zn NMR reveals short-range disorder in zeolitic imidazolate framework glasses.

Authors:  Rasmus S K Madsen; Ang Qiao; Jishnu Sen; Ivan Hung; Kuizhi Chen; Zhehong Gan; Sabyasachi Sen; Yuanzheng Yue
Journal:  Science       Date:  2020-03-27       Impact factor: 47.728

  1 in total

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