Literature DB >> 26161949

Palladium-Catalyzed Oxalyl Amide Directed Silylation and Germanylation of Amine Derivatives.

Changpeng Chen1, Mingyu Guan1, Jingyu Zhang, Zhenkang Wen2, Yingsheng Zhao1.   

Abstract

Palladium-catalyzed direct ortho-silylation of oxalyl amide-protected phenylmethanamine and phenethylamine with commercially available disilanes is reported. Germanylation products were also produced under the same reaction conditions. This protocol tolerated oxalyl amide-protected aliphatic amines, which gave γ-C-H silylation products.

Entities:  

Year:  2015        PMID： 26161949     DOI： 10.1021/acs.orglett.5b01393

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

1.  Rhodium-Catalyzed Regioselective Silylation of Alkyl C-H Bonds for the Synthesis of 1,4-Diols.

Authors:  Caleb Karmel; Bijie Li; John F Hartwig
Journal:  J Am Chem Soc       Date:  2018-01-22       Impact factor: 15.419

2.  Iridium-Catalyzed Silylation of Unactivated C-H Bonds.

Authors:  John F Hartwig; Erik A Romero
Journal:  Tetrahedron       Date:  2019-05-27       Impact factor: 2.457

Review 3.  Inorganometallics (Transition Metal-Metalloid Complexes) and Catalysis.

Authors:  Bogdan Marciniec; Cezary Pietraszuk; Piotr Pawluć; Hieronim Maciejewski
Journal:  Chem Rev       Date:  2021-12-30       Impact factor: 60.622

4.  Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds.

Authors:  Taegyo Lee; John F Hartwig
Journal:  Angew Chem Int Ed Engl       Date:  2016-06-02       Impact factor: 15.336

Review 5.  A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Authors:  Carlo Sambiagio; David Schönbauer; Remi Blieck; Toan Dao-Huy; Gerit Pototschnig; Patricia Schaaf; Thomas Wiesinger; Muhammad Farooq Zia; Joanna Wencel-Delord; Tatiana Besset; Bert U W Maes; Michael Schnürch
Journal:  Chem Soc Rev       Date:  2018-08-28       Impact factor: 54.564
  5 in total

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