Literature DB >> 26158867

Rh-Catalyzed Domino Addition-Enolate Arylation: Generation of 3-Substituted Oxindoles via a Rh(lll) Intermediate.

Young Jin Jang1, Hyung Yoon1, Mark Lautens1.   

Abstract

A Rh-catalyzed domino conjugate addition-arylation sequence via a Rh(III) intermediate is reported. This process involving a proposed intramolecular oxidative addition of a rhodium enolate was utilized to achieve the synthesis of 3-substituted oxindole derivatives in moderate to excellent yields.

Entities:  

Year:  2015        PMID: 26158867     DOI: 10.1021/acs.orglett.5b01737

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Sequential catalysis: exploiting a single rhodium(i) catalyst to promote an alkyne hydroacylation-aryl boronic acid conjugate addition sequence.

Authors:  Maitane Fernández; Matthias Castaing; Michael C Willis
Journal:  Chem Sci       Date:  2016-09-09       Impact factor: 9.825

2.  Selective synthesis of unsymmetric dibenzo[a,e]pentalenes by a rhodium-catalysed stitching reaction.

Authors:  Keisuke Takahashi; Shingo Ito; Ryo Shintani; Kyoko Nozaki
Journal:  Chem Sci       Date:  2016-11-14       Impact factor: 9.825

  2 in total

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