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Literature DB >> 26154719

[Cp*RhCl2]2: mechanosynthesis and applications in C-H bond functionalisations under ball-milling conditions.

Abstract

A mechanochemical synthesis of [Cp*RhCl2]2 has been developed. Under LAG conditions the organometallic complex can be prepared in a shorter reaction time compared to the standard solution-based protocol. The obtained Rh(iii) dimer is then applicable as catalyst in subsequent solvent-free mechanochemical C-H bond functionalisations of 2-phenylpyridine.

Entities: Chemical

Year: 2015 PMID： 26154719 DOI： 10.1039/c5cc04423e

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

7 in total

1. Mechanochemical halogenation of unsymmetrically substituted azobenzenes.

Authors: Dajana Barišić; Mario Pajić; Ivan Halasz; Darko Babić; Manda Ćurić
Journal: Beilstein J Org Chem Date: 2022-06-15 Impact factor: 2.544

2. Manganese-catalyzed allylation via sequential C-H and C-C/C-Het bond activation.

Authors: Qingquan Lu; Felix J R Klauck; Frank Glorius
Journal: Chem Sci Date: 2017-02-24 Impact factor: 9.825

Review 3. Mechanochemistry: A Force of Synthesis.

Authors: Jean-Louis Do; Tomislav Friščić
Journal: ACS Cent Sci Date: 2016-12-29 Impact factor: 14.553

4. Palladium-catalyzed ortho-halogenations of acetanilides with N-halosuccinimides via direct sp² C-H bond activation in ball mills.

Authors: Zi Liu; Hui Xu; Guan-Wu Wang
Journal: Beilstein J Org Chem Date: 2018-02-16 Impact factor: 2.883

[Cp*RhCl2]2: mechanosynthesis and applications in C-H bond functionalisations under ball-milling conditions.

1. Mechanochemical halogenation of unsymmetrically substituted azobenzenes.

2. Manganese-catalyzed allylation via sequential C-H and C-C/C-Het bond activation.

Review 3. Mechanochemistry: A Force of Synthesis.

4. Palladium-catalyzed ortho-halogenations of acetanilides with N-halosuccinimides via direct sp² C-H bond activation in ball mills.

Review 5. Mechanochemical synthesis of small organic molecules.

Review 6. Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber.

Review 7. Mechanochemical Organocatalysis: Do High Enantioselectivities Contradict What We Might Expect?

[Cp*RhCl2]2: mechanosynthesis and applications in C-H bond functionalisations under ball-milling conditions.

1. Mechanochemical halogenation of unsymmetrically substituted azobenzenes.

2. Manganese-catalyzed allylation via sequential C-H and C-C/C-Het bond activation.

Review 3. Mechanochemistry: A Force of Synthesis.

4. Palladium-catalyzed ortho-halogenations of acetanilides with N-halosuccinimides via direct sp2 C-H bond activation in ball mills.

Review 5. Mechanochemical synthesis of small organic molecules.

Review 6. Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber.

Review 7. Mechanochemical Organocatalysis: Do High Enantioselectivities Contradict What We Might Expect?

4. Palladium-catalyzed ortho-halogenations of acetanilides with N-halosuccinimides via direct sp² C-H bond activation in ball mills.