| Literature DB >> 26149891 |
Yanlan Wang1, Pierre-Alexandre Deyris1, Tatiana Caneque1, Florent Blanchard1, Yanling Li2, Franca Bigi3, Raimondo Maggi3, Sebastien Blanchard2, Giovanni Maestri4,5, Max Malacria1,2.
Abstract
A simple synthetic method allows the one-pot assembly of C3 -symmetric, 44-core-valence-electron, triangular Pd or Pt clusters and their heterobimetallic mixed Pd/Pt analogues. These mixed metal complexes are the first examples of stable triangular all-metal heteroaromatics. In contrast to traditional heteroaromatic molecules formed combining main-group elements, they actually retain structural and electronic features of their homonuclear analogues.Entities:
Keywords: aromaticity; cluster compounds; heterocycles; metal-metal bonds; metallacycles
Year: 2015 PMID： 26149891 DOI： 10.1002/chem.201501239
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236