Literature DB >> 26139520

UV photoexcitation of a dissolved metalloid Ge9 cluster compound and its extensive ultrafast response.

M Klinger1, C Schenk, F Henke, A Clayborne, A Schnepf, A-N Unterreiner.   

Abstract

Femtosecond pump-probe absorption spectroscopy in tetrahydrofuran solution has been used to investigate the dynamics of a metalloid cluster compound {Ge9[Si(SiMe3)3]3}(-). Upon UV photoexcitation, the transients in the near-infrared spectral region showed signatures reminiscent of excess electrons in THF (bound or quasi-free) whereas in the visible part excited state dynamics of the cluster complex dominates.

Entities:  

Year:  2015        PMID: 26139520     DOI: 10.1039/c5cc04513d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Photoexcitation of Ge9- Clusters in THF: New Insights into the Ultrafast Relaxation Dynamics and the Influence of the Cation.

Authors:  Nadine C Michenfelder; Christian Gienger; Melina Dilanas; Andreas Schnepf; Andreas-Neil Unterreiner
Journal:  Molecules       Date:  2020-06-05       Impact factor: 4.411

  1 in total

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