Literature DB >> 26138871

Dynamic Formation of Noncovalent Calixsalen Aggregates.

Małgorzata Petryk1,2, Anna Troć3, Błażej Gierczyk1, Witold Danikiewicz4, Marcin Kwit5,6.   

Abstract

A procedure for studying "dynamic structural behavior" of large chiral macrocycles is presented. Ion mobility MS, diffusion-ordered NMR spectroscopy (DOSY NMR), and optical rotation (OR) measurements, supported by calculations, are used together as effective complementary methods to study dynamic formation of noncovalent aggregates. It is shown that the monomer-dimer equilibrium is driven by π-π or CH-π interactions and controlled largely by the substitution pattern of the calixsalen skeleton.
© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  NMR; calixsalens; ion mobility MS; optical rotation; self‐assembly

Year:  2015        PMID： 26138871     DOI： 10.1002/chem.201500945

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  3 in total

1.  Surprising solvent-induced structural rearrangements in large [N···I+···N] halogen-bonded supramolecular capsules: an ion mobility-mass spectrometry study.

Authors:  Ulrike Warzok; Mateusz Marianski; Waldemar Hoffmann; Lotta Turunen; Kari Rissanen; Kevin Pagel; Christoph A Schalley
Journal:  Chem Sci       Date:  2018-09-05       Impact factor: 9.825

2.  Specific Noncovalent Association of Truncated exo-Functionalized Triangular Homochiral Isotrianglimines through Head-to-Head, Tail-to-Tail, and Honeycomb Supramolecular Motifs.

Authors:  Agnieszka Janiak; Jadwiga Gajewy; Joanna Szymkowiak; Błażej Gierczyk; Marcin Kwit
Journal:  J Org Chem       Date:  2022-01-14       Impact factor: 4.354

Review 3.  Imine- and Amine-Type Macrocycles Derived from Chiral Diamines and Aromatic Dialdehydes.

Authors:  Jerzy Lisowski
Journal:  Molecules       Date:  2022-06-25       Impact factor: 4.927
  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.