Literature DB >> 26136166

Tandem Chemoselective Suzuki-Miyaura Cross-Coupling Enabled by Nucleophile Speciation Control.

Ciaran P Seath1, James W B Fyfe1, John J Molloy1, Allan J B Watson2.   

Abstract

Control of boronic acid speciation is presented as a strategy to achieve nucleophile chemoselectivity in the Suzuki-Miyaura reaction. Combined with simultaneous control of oxidative addition and transmetalation, this enables chemoselective formation of two C-C bonds in a single operation, providing a method for the rapid preparation of highly functionalized carbogenic frameworks.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  boron; chemoselectivity; cross-coupling; palladium; speciation

Mesh：

Substances：

Year:  2015        PMID： 26136166     DOI： 10.1002/anie.201504297

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  13 in total

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