| Literature DB >> 26125090 |
Qingquan Lu1, Zhiliang Liu1, Yi Luo1, Guanghui Zhang1, Zhiyuan Huang1, Huamin Wang1, Chao Liu1,2, Jeffrey T Miller3,2, Aiwen Lei1,4,2.
Abstract
A highly selective radical dioxygenation of alkenes using hydroxamic acid and O2 was developed, and copper/cobalt was used as the catalyst without assistance of any additional ligands or bases. Mechanistic investigation disclosed that copper salt and O2 work in concert to activate hydroxamic acid, with Cu(I) and Cu(II) concurrently existing in this reaction.Entities:
Year: 2015 PMID： 26125090 DOI： 10.1021/acs.orglett.5b01223
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005