| Literature DB >> 26125068 |
Siyu Guo1, Peng Yang, Jianrong Steve Zhou.
Abstract
Asymmetric transfer hydrogenation of electron-deficient olefins is realized with nickel catalysts supported by strongly σ-donating bisphosphines. Deuterium labeling experiments point to a reaction sequence of formate decarboxylation, asymmetric hydride insertion and non-stereoselective protonation of resulting nickel enolates.Entities:
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Year: 2015 PMID： 26125068 DOI： 10.1039/c5cc01632k
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222