| Literature DB >> 26109330 |
Shizuka Nishiyama1, Ko Urushibara1, Hyuma Masu2, Isao Azumaya3, Hiroyuki Kagechika4, Aya Tanatani1.
Abstract
Cyclic triamides bearing amidino groups at the meta position of the phenyl rings were synthesized, and their conformational properties in the crystal and in solution were examined. Compound exists as a capsule-type dimer of the enantiomers with a bowl-shaped syn conformation in the crystal state. Compound exists mainly in the syn form in solution, and chiral induction was observed upon addition of a chiral acid to a solution of.Entities:
Keywords: chiral induction; crystal structure; cyclic amide; dimer, capsule
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Year: 2015 PMID： 26109330 DOI： 10.1002/chir.22476
Source DB: PubMed Journal: Chirality ISSN： 0899-0042 Impact factor: 2.437