Literature DB >> 26101889

B(C6F5)3-Catalyzed Hydrodesulfurization Using Hydrosilanes--Metal-Free Reduction of Sulfides.

Kodai Saito1, Kazumi Kondo1, Takahiko Akiyama1.   

Abstract

B(C6F5)3-catalyzed hydrodesulfurization of carbon-sulfur bonds was achieved using triethylsilane as the reducing agent. The corresponding products were obtained in good yields under mild reaction conditions. This protocol could be applied to the reduction of sulfides, including benzyl and alkyl sulfides and dithianes, with high chemoselectivities.

Entities:  

Year:  2015        PMID: 26101889     DOI: 10.1021/acs.orglett.5b01651

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  4 in total

1.  Chemo- and Diastereoselective Hydrosilylation of Amorphadiene toward the Synthesis of Artemisinin.

Authors:  Geoffrey Schwertz; Andrea Zanetti; Marllon Nascimento de Oliveira; Mario Andrés Gomez Fernandez; Zacharias Amara; Janine Cossy
Journal:  J Org Chem       Date:  2020-07-09       Impact factor: 4.354

2.  A selective removal of the secondary hydroxy group from ortho-dithioacetal-substituted diarylmethanols.

Authors:  Anna Czarnecka; Emilia Kowalska; Agnieszka Bodzioch; Joanna Skalik; Marek Koprowski; Krzysztof Owsianik; Piotr Bałczewski
Journal:  Beilstein J Org Chem       Date:  2018-05-29       Impact factor: 2.883

Review 3.  Tris(pentafluorophenyl)borane-Catalyzed Reactions Using Silanes.

Authors:  Taylor Hackel; Nicholas A McGrath
Journal:  Molecules       Date:  2019-01-25       Impact factor: 4.411

Review 4.  Defunctionalisation catalysed by boron Lewis acids.

Authors:  Huaquan Fang; Martin Oestreich
Journal:  Chem Sci       Date:  2020-07-28       Impact factor: 9.825

  4 in total

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