| Literature DB >> 26099041 |
Cassandra A Zentner1, Holden W H Lai, Joshua T Greenfield, Ren A Wiscons, Matthias Zeller, Charles F Campana, Orhan Talu, Stephen A FitzGerald, Jesse L C Rowsell.
Abstract
1,3,5-Tris(4-carboxyphenyl)benzene assembles into an intricate 8-fold polycatenated assembly of (6,3) hexagonal nets formed through hydrogen bonds and π-stacking. One polymorph features 56 independent molecules in the asymmetric unit, the largest Z' reported to date. The framework is permanently porous, with a BET surface area of 1095 m(2) g(-1) and readily adsorbs N2, H2 and CO2.Entities:
Year: 2015 PMID： 26099041 DOI： 10.1039/c5cc04219d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222