Literature DB >> 26095086

Gallium fluoroarsenates.

Kayleigh L Marshall1, Jennifer A Armstrong, Mark T Weller.   

Abstract

Six new phases in the gallium-fluoride-arsenate system have been synthesised hydrofluorothermally using a fluoride-rich medium and "HAsF6" (HF : AsF5) as a reactant. RbGaF3(H2AsO4), KGaF(H2AsO4) and [piperazine-H2]2[Ga2F8(HAsO4)]·H2O have one dimensional structures, [DABCO-H2]2[Ga4F7O2H(AsO4)2]·4H2O consists of two dimensionally connected polyhedral layers, while GaF(AsO3[OH,F])2 and (NH4)3Ga4F9(AsO4)2 both have three-dimensionally connected polyhedral frameworks.

Entities:  

Year:  2015        PMID: 26095086     DOI: 10.1039/c5dt01094b

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  1 in total

1.  Two new Rb-Ga arsenates: RbGa(HAsO4)2 and RbGa2As(HAsO4)6.

Authors:  Karolina Schwendtner; Uwe Kolitsch
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2018-08-14
  1 in total

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