A Luminescent Hypercrosslinked Conjugated Microporous Polymer for Efficient Removal and Detection of Mercury Ions.

A hypercrosslinked conjugated microporous polymer (HCMP-1) with a robustly efficient absorption and highly specific sensitivity to mercury ions (Hg(2+)) is synthesized in a one-step Friedel-Crafts alkylation of cost-effective 2,4,6-trichloro-1,3,5-triazine and dibenzofuran in 1,2-dichloroethane. HCMP-1 has a moderate Brunauer-Emmett-Teller specific surface (432 m(2) g(-1)), but it displays a high adsorption affinity (604 mg g(-1)) and excellent trace efficiency for Hg(2+). The π-π* electronic transition among the aromatic heterocyclic rings endows HCMP-1 a strong fluorescent property and the fluorescence is obviously weakened after Hg(2+) uptake, which makes the hypercrosslinked conjugated microporous polymer a promising fluorescent probe for Hg(2+) detection, owning a super-high sensitivity (detection limit 5 × 10(-8) mol L(-1)).