Literature DB >> 26087458

Gas promotes the crystallization of nano-sized metal-organic frameworks in ionic liquid.

Chengcheng Liu1, Bingxing Zhang, Jianling Zhang, Li Peng, Xinchen Kang, Buxing Han, Tianbin Wu, Xinxin Sang, Xue Ma.   

Abstract

Herein it was found that gas can be utilized as an activator to promote metal-organic framework (MOF) crystallization in IL at room temperature. The ultra-small MOF nanoparticles were obtained, and their size and porosity properties can be easily modulated by controlling gas pressure. The as-synthesized nano-sized Cu-MOF is an excellent candidate catalyst for the solvent-free oxidation of cyclohexene with oxygen.

Entities:  

Year:  2015        PMID: 26087458     DOI: 10.1039/c5cc02503f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

Review 1.  Recent Progress of Nanoscale Metal-Organic Frameworks in Synthesis and Battery Applications.

Authors:  Ming Zhong; Lingjun Kong; Kun Zhao; Ying-Hui Zhang; Na Li; Xian-He Bu
Journal:  Adv Sci (Weinh)       Date:  2020-12-31       Impact factor: 16.806

  1 in total

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