Literature DB >> 26077621

Complex transition metal hydrides: linear correlation of countercation electronegativity versus T-D bond lengths.

T D Humphries1, D A Sheppard, C E Buckley.   

Abstract

For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T-deuterium bond length (T = Fe, Co, Ni) and the average electronegativity of the metal countercations. This relationship can be further employed towards aiding structural solutions and predicting physical properties of novel complex transition metal hydrides.

Entities:  

Year:  2015        PMID: 26077621     DOI: 10.1039/c5cc03654b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Molecular Adsorption of H2 on Small Neutral Silver-Copper Bimetallic Nanoparticles: A Search for Novel Hydrogen Storage Materials.

Authors:  Sathya M Perera; Samanthika R Hettiarachchi; Jinasena W Hewage
Journal:  ACS Omega       Date:  2022-01-07
  1 in total

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