Literature DB >> 26070029

Formal Total Synthesis of Echinopines A and B via Cr(0)-Promoted [6π + 2π] Cycloaddition.

Saptarshi De1, Shilpi Misra1, James H Rigby1.   

Abstract

A concise formal synthesis of echinopines A and B is reported. The key [5.5.7] tricyclic intermediate, which has been previously used for the synthesis of echinopine A and B, was assembled using Cr(0)-promoted photochemical [6π + 2π] cycloaddition followed by a radical cyclization step.

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Year:  2015        PMID: 26070029     DOI: 10.1021/acs.orglett.5b01326

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Ready Access to the Echinopines Skeleton via Gold(I)-Catalyzed Alkoxycyclizations of Enynes.

Authors:  Ruth Dorel; Antonio M Echavarren
Journal:  J Org Chem       Date:  2016-08-26       Impact factor: 4.354

  1 in total

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