Literature DB >> 26068401

Bis(zinc porphyrin) as a CD-sensitive bidentate host molecule: direct determination of absolute configuration of mono-alcohols.

Satoshi Hayashi1, Miku Yotsukura, Masahiro Noji, Toshikatsu Takanami.   

Abstract

A facile and direct protocol to determine the absolute configurations of chiral mono-alcohols without analyte derivatization can now be realized using a novel circular dichroic (CD)-sensitive bis(zinc porphyrin) BP1 host system. The binding of mono-alcohols to BP1 should be greatly enhanced by the simultaneous double coordination of the hydroxyl group to the two central metals of the porphyrin subunits.

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Year:  2015        PMID： 26068401     DOI： 10.1039/c5cc03303a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Diasteroselective multi-component assemblies from dynamic covalent imine condensation and metal-coordination chemistry: mechanism and narcissistic stereochemistry self-sorting.

Authors:  Elena Badetti; Nadia Alessandra Carmo Dos Santos; Francesca A Scaramuzzo; Carlo Bravin; Klaus Wurst; Giulia Licini; Cristiano Zonta
Journal:  RSC Adv       Date:  2018-05-29       Impact factor: 4.036

2.  Host-guest assembly for highly sensitive probing of a chiral mono-alcohol with a zinc trisporphyrinate.

Authors:  Cong-Cong Zhuo; Li Li; Chuan-Jiang Hu; Jian-Ping Lang
Journal:  Sci Rep       Date:  2017-06-19       Impact factor: 4.379

3.  Optical Activity and Helicity Enhancement of Highly Sensitive Dinaphthylmethane-Based Stereodynamic Probes for Secondary Alcohols.

Authors:  Tomasz Mądry; Agnieszka Czapik; Marcin Kwit
Journal:  ACS Omega       Date:  2019-02-14

4.  Self-Assembly of Chiral Cyclohexanohemicucurbit[n]urils with Bis(Zn Porphyrin): Size, Shape, and Time-Dependent Binding.

Authors:  Marko Šakarašvili; Lukas Ustrnul; Elina Suut; Jagadeesh Varma Nallaparaju; Kamini A Mishra; Nele Konrad; Jasper Adamson; Victor Borovkov; Riina Aav
Journal:  Molecules       Date:  2022-01-29       Impact factor: 4.411

5.  Synthesis and Properties of Bis-Porphyrin Molecular Tweezers: Effects of Spacer Flexibility on Binding and Supramolecular Chirogenesis.

Authors:  Magnus Blom; Sara Norrehed; Claes-Henrik Andersson; Hao Huang; Mark E Light; Jonas Bergquist; Helena Grennberg; Adolf Gogoll
Journal:  Molecules       Date:  2015-12-23       Impact factor: 4.411

Review 6.  BODIPY- and Porphyrin-Based Sensors for Recognition of Amino Acids and Their Derivatives.

Authors:  Marco Farinone; Karolina Urbańska; Miłosz Pawlicki
Journal:  Molecules       Date:  2020-10-02       Impact factor: 4.411
  6 in total

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