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Literature DB >> 26065318

Tetradecanuclear Iron(III)-Oxo Nanoclusters Stabilized by Trilacunary Heteropolyanions.

Masooma Ibrahim¹, Ali Haider¹, Yixian Xiang¹, Bassem S Bassil^1,2, Akina M Carey¹, Lisa Rullik¹, Geoffrey B Jameson³, Floriant Doungmene⁴, Israël M Mbomekallé⁴, Pedro de Oliveira⁴, Valeriu Mereacre⁵, George E Kostakis⁶, Annie K Powell^5,7, Ulrich Kortz¹.

Abstract

The tetrameric, multi-Fe(III)-containing polyoxotungstates [Fe14O6(OH)13(P2W15O56)4](31-) (1) and [Na2Fe14(OH)12(PO4)4(A-α-XW9O34)4](20-) (X = Si(IV) (2), Ge(IV) (3)) have been successfully synthesized under conventional reaction conditions in aqueous, slightly acidic (1), or basic (2 and 3) media. Polyanions 1-3 were characterized in the solid state by single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric analysis, and magnetic studies, and in solution by electrochemistry.

Entities: Chemical Species

Year: 2015 PMID： 26065318 DOI： 10.1021/acs.inorgchem.5b00124

Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165

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Cited

3 in total

1. Incorporating polyoxometalates and organic ligands to pursue 3d-4f heterometallic clusters: a series of {Cr₄Ln₄} clusters stabilized by phthalic acid and [SiW₁₂O₄₀]⁴.

Authors: Ya-Nan Gu; Dan Zhao; Hao Yu; Rui Ge; Zhong Li; Chong-Bian Tian; Xin-Xiong Li; Yan-Qiong Sun; Shou-Tian Zheng
Journal: RSC Adv Date: 2019-05-01 Impact factor: 3.361

2. Synthesis and Characterization of a Heterometallic Extended Architecture Based on a Manganese(II)-Substituted Sandwich-Type Polyoxotungstate.

Authors: Masooma Ibrahim; Eufemio Moreno-Pineda; Thomas Bergfeldt; Christopher E Anson; Annie K Powell
Journal: Materials (Basel) Date: 2018-01-17 Impact factor: 3.623

3. Syntheses, Crystal Structure, Electrocatalytic, and Magnetic Properties of the Monolanthanide-Containing Germanotungstates [Ln(H₂O) _n GeW₁₁O₃₉]^5- (Ln = Dy, Er, n = 4,3).

Authors: Masooma Ibrahim; Israël M Mbomekallé; Pedro de Oliveira; Ananya Baksi; Anthony B Carter; Yan Peng; Thomas Bergfeldt; Sharali Malik; Christopher E Anson
Journal: ACS Omega Date: 2019-12-10

3 in total

Tetradecanuclear Iron(III)-Oxo Nanoclusters Stabilized by Trilacunary Heteropolyanions.

1. Incorporating polyoxometalates and organic ligands to pursue 3d-4f heterometallic clusters: a series of {Cr4Ln4} clusters stabilized by phthalic acid and [SiW12O40]4.

2. Synthesis and Characterization of a Heterometallic Extended Architecture Based on a Manganese(II)-Substituted Sandwich-Type Polyoxotungstate.

3. Syntheses, Crystal Structure, Electrocatalytic, and Magnetic Properties of the Monolanthanide-Containing Germanotungstates [Ln(H2O) n GeW11O39]5- (Ln = Dy, Er, n = 4,3).

1. Incorporating polyoxometalates and organic ligands to pursue 3d-4f heterometallic clusters: a series of {Cr₄Ln₄} clusters stabilized by phthalic acid and [SiW₁₂O₄₀]⁴.

3. Syntheses, Crystal Structure, Electrocatalytic, and Magnetic Properties of the Monolanthanide-Containing Germanotungstates [Ln(H₂O) _n GeW₁₁O₃₉]^5- (Ln = Dy, Er, n = 4,3).