Literature DB >> 26057152

Comparative Study of Ether-Based Electrolytes for Application in Lithium-Sulfur Battery.

Lorenzo Carbone1, Mallory Gobet, Jing Peng2, Matthew Devany3, Bruno Scrosati4, Steve Greenbaum, Jusef Hassoun1.   

Abstract

Herein, we report the characteristics of electrolytes using various ether-solvents with molecular composition CH3O[CH2CH2O]nCH3, differing by chain length, and LiCF3SO3 as the lithium salt. The electrolytes, considered as suitable media for lithium-sulfur batteries, are characterized in terms of thermal properties (TGA, DSC), lithium ion conductivity, lithium interface stability, cyclic voltammetry, self-diffusion properties of the various components, and lithium transference number measured by NMR. Furthermore, the electrolytes are characterized in lithium cells using a sulfur-carbon composite cathode by galvanostatic charge-discharge tests. The results clearly evidence the influence of the solvent chain length on the species mobility within the electrolytes that directly affects the behavior in lithium sulfur cell. The results may effectively contribute to the progress of an efficient, high-energy lithium-sulfur battery.

Entities:  

Keywords:  NMR; diffusion; electrolytes; ether-based; glyme; lithium−sulfur battery

Mesh:

Substances:

Year:  2015        PMID: 26057152     DOI: 10.1021/acsami.5b02160

Source DB:  PubMed          Journal:  ACS Appl Mater Interfaces        ISSN: 1944-8244            Impact factor:   9.229


  8 in total

1.  Amorphous MoS3 as the sulfur-equivalent cathode material for room-temperature Li-S and Na-S batteries.

Authors:  Hualin Ye; Lu Ma; Yu Zhou; Lu Wang; Na Han; Feipeng Zhao; Jun Deng; Tianpin Wu; Yanguang Li; Jun Lu
Journal:  Proc Natl Acad Sci U S A       Date:  2017-11-27       Impact factor: 11.205

2.  Solvent selection criteria for temperature-resilient lithium-sulfur batteries.

Authors:  Guorui Cai; John Holoubek; Mingqian Li; Hongpeng Gao; Yijie Yin; Sicen Yu; Haodong Liu; Tod A Pascal; Ping Liu; Zheng Chen
Journal:  Proc Natl Acad Sci U S A       Date:  2022-07-05       Impact factor: 12.779

3.  Sulfur encapsulated in thermally reduced graphite oxide as a cathode for Li-S batteries.

Authors:  Xinbo Xu; Jiafeng Ruan; Yuepeng Pang; Tao Yuan; Shiyou Zheng
Journal:  RSC Adv       Date:  2018-01-31       Impact factor: 4.036

4.  Route to sustainable lithium-sulfur batteries with high practical capacity through a fluorine free polysulfide catholyte and self-standing Carbon Nanofiber membranes.

Authors:  Du-Hyun Lim; Marco Agostini; Florian Nitze; James Manuel; Jou-Hyeon Ahn; Aleksandar Matic
Journal:  Sci Rep       Date:  2017-07-24       Impact factor: 4.379

5.  Remarkable Effect of [Li(G4)]TFSI Solvate Ionic Liquid (SIL) on the Regio- and Stereoselective Ring Opening of α-Gluco Carbasugar 1,2-Epoxides.

Authors:  Sebastiano Di Pietro; Vittorio Bordoni; Andrea Mezzetta; Cinzia Chiappe; Giovanni Signore; Lorenzo Guazzelli; Valeria Di Bussolo
Journal:  Molecules       Date:  2019-08-14       Impact factor: 4.411

6.  Mesoporous TiO2 coating on carbon-sulfur cathode for high capacity Li-sulfur battery.

Authors:  Ruchira Dharmasena; Arjun Kumar Thapa; Ram Krishna Hona; Jacek Jasinski; Mahendra K Sunkara; Gamini U Sumanasekera
Journal:  RSC Adv       Date:  2018-03-26       Impact factor: 3.361

7.  Tuning the morphology of sulfur-few layer graphene composites via liquid phase evaporation for battery application.

Authors:  Eleonora Venezia; Lorenzo Carbone; Francesco Bonaccorso; Vittorio Pellegrini
Journal:  Nanoscale Adv       Date:  2022-01-13

8.  Lithium-Metal Batteries Using Sustainable Electrolyte Media and Various Cathode Chemistries.

Authors:  Vittorio Marangon; Luca Minnetti; Matteo Adami; Alberto Barlini; Jusef Hassoun
Journal:  Energy Fuels       Date:  2021-05-20       Impact factor: 3.605

  8 in total

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