Literature DB >> 26039540

Fluorine-Rich Fluorides: New Insights into the Chemistry of Polyfluoride Anions.

Thomas Vent-Schmidt1, Felix Brosi2, Jens Metzger1, Tobias Schlöder2, Xuefeng Wang3, Lester Andrews3, Carsten Müller4, Helmut Beckers2, Sebastian Riedel5.   

Abstract

Polyfluoride anions have been investigated by matrix-isolation spectroscopy and quantum-chemical methods. For the first time the higher polyfluoride anion [F5 ](-) has been observed under cryogenic conditions in neon matrices at 850 cm(-1) . In addition, a new band for the Cs(+) [F3 ](-) complex in neon is reported.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  cesium fluorides; coupled-cluster calculations; fluorides; matrix-isolation spectroscopy; polyfluoride anions

Year:  2015        PMID： 26039540     DOI： 10.1002/anie.201502624

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  2 in total

Review 1.  Understanding Periodic and Non-periodic Chemistry in Periodic Tables.

Authors:  Changsu Cao; René E Vernon; W H Eugen Schwarz; Jun Li
Journal:  Front Chem       Date:  2021-01-06       Impact factor: 5.221

2.  Investigation of Molecular Alkali Tetrafluorido Aurates by Matrix-Isolation Spectroscopy.

Authors:  Frenio A Redeker; Mathias A Ellwanger; Helmut Beckers; Sebastian Riedel
Journal:  Chemistry       Date:  2019-10-24       Impact factor: 5.236
  2 in total

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