Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Facile Protocol for Catalytic Frustrated Lewis Pair Hydrogenation and Reductive Deoxygenation of Ketones and Aldehydes.

Literature DB >> 26038152

Facile Protocol for Catalytic Frustrated Lewis Pair Hydrogenation and Reductive Deoxygenation of Ketones and Aldehydes.

Abstract

A series of ketones and aldehydes are reduced in toluene under H2 in the presence of 5 mol % B(C6F5)3 and either cyclodextrin or molecular sieves affording a facile metal-free protocol for reduction to alcohols. Similar treatment of aryl ketones resulted in metal-free deoxygenation yielding aromatic hydrocarbons.

Entities: Chemical

Keywords: boranes; deoxygenation; frustrated Lewis pairs; hydrogenation

Year: 2015 PMID： 26038152 DOI： 10.1002/anie.201503087

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

Keyword Cloud
Cited

14 in total

1. β-Hydroxy-tetrahydroquinolines from Quinolines Using Chloroborane: Synthesis of the Peptidomimetic FISLE-412.

Authors: Ahmad S Altiti; Kai Fan Cheng; Mingzhu He; Yousef Al-Abed
Journal: Chemistry Date: 2017-07-26 Impact factor: 5.236

2. Optimizing the Energetics of FLP-Type H₂ Activation by Modulating the Electronic and Structural Properties of the Lewis Acids: A DFT Study.

Authors: Mojgan Heshmat; Bernd Ensing
Journal: J Phys Chem A Date: 2020-07-29 Impact factor: 2.781

3. Versatile Catalytic Hydrogenation Using A Simple Tin(IV) Lewis Acid.

Authors: Daniel J Scott; Nicholas A Phillips; Joshua S Sapsford; Arron C Deacy; Matthew J Fuchter; Andrew E Ashley
Journal: Angew Chem Int Ed Engl Date: 2016-10-24 Impact factor: 15.336

4. Metal-free electrocatalytic hydrogen oxidation using frustrated Lewis pairs and carbon-based Lewis acids.

Authors: Elliot J Lawrence; Ewan R Clark; Liam D Curless; James M Courtney; Robin J Blagg; Michael J Ingleson; Gregory G Wildgoose
Journal: Chem Sci Date: 2016-01-06 Impact factor: 9.825

5. Expanding Water/Base Tolerant Frustrated Lewis Pair Chemistry to Alkylamines Enables Broad Scope Reductive Aminations.

Authors: Valerio Fasano; Michael J Ingleson
Journal: Chemistry Date: 2017-01-18 Impact factor: 5.236

Facile Protocol for Catalytic Frustrated Lewis Pair Hydrogenation and Reductive Deoxygenation of Ketones and Aldehydes.

1. β-Hydroxy-tetrahydroquinolines from Quinolines Using Chloroborane: Synthesis of the Peptidomimetic FISLE-412.

2. Optimizing the Energetics of FLP-Type H₂ Activation by Modulating the Electronic and Structural Properties of the Lewis Acids: A DFT Study.

3. Versatile Catalytic Hydrogenation Using A Simple Tin(IV) Lewis Acid.

4. Metal-free electrocatalytic hydrogen oxidation using frustrated Lewis pairs and carbon-based Lewis acids.

5. Expanding Water/Base Tolerant Frustrated Lewis Pair Chemistry to Alkylamines Enables Broad Scope Reductive Aminations.

6. Solid state frustrated Lewis pair chemistry.

7. Direct Reductive Amination of Carbonyl Compounds Catalyzed by a Moisture Tolerant Tin(IV) Lewis Acid.

Review 8. Defunctionalisation catalysed by boron Lewis acids.

9. Facile Protocol for Water-Tolerant "Frustrated Lewis Pair"-Catalyzed Hydrogenation.

10. Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO₂.