Literature DB >> 26035305

Magnetic criteria of aromaticity.

Renana Gershoni-Poranne1, Amnon Stanger.   

Abstract

This review describes the current state of magnetic criteria of aromaticity. The introduction contains the fundamentals of ring currents in aromatic and antiaromatic systems, followed by a brief description of experimental and computational tools: NMR, diamagnetic susceptibility exaltation, current density analyses (CDA) and nucleus independent chemical shifts (NICS). This is followed by more comprehensive chapters: NMR - focusing on the work of R. Mitchell - NICS and CDA - describing the progress and development of the methods to their current state and presenting some examples of representative work.

Year:  2015        PMID: 26035305     DOI: 10.1039/c5cs00114e

Source DB:  PubMed          Journal:  Chem Soc Rev        ISSN: 0306-0012            Impact factor:   54.564


  27 in total

1.  Substantial π-aromaticity in the anionic heavy-metal cluster [Th@Bi12]4.

Authors:  Armin R Eulenstein; Yannick J Franzke; Niels Lichtenberger; Robert J Wilson; H Lars Deubner; Florian Kraus; Rodolphe Clérac; Florian Weigend; Stefanie Dehnen
Journal:  Nat Chem       Date:  2020-12-07       Impact factor: 24.427

2.  Hyperconjugative Antiaromaticity Activates 4H-Pyrazoles as Inverse-Electron-Demand Diels-Alder Dienes.

Authors:  Brian J Levandowski; Nile S Abularrage; K N Houk; Ronald T Raines
Journal:  Org Lett       Date:  2019-10-07       Impact factor: 6.005

3.  Planar ten-membered 10-π-electron aromatic (CH)5(XH)5 {X = Ge, Sn} systems.

Authors:  Sukanta Mondal; Pallavi Sarkar; Alvaro Muñoz-Castro
Journal:  J Mol Model       Date:  2018-08-31       Impact factor: 1.810

4.  Molecular Magnetizabilities Computed Via Finite Fields: Assessing Alternatives to MP2 and Revisiting Magnetic Exaltations in Aromatic and Antiaromatic Species.

Authors:  Tim Stauch; Brad Ganoe; Jonathan Wong; Joonho Lee; Adam Rettig; Jiashu Liang; Jie Li; Evgeny Epifanovsky; Teresa Head-Gordon; Martin Head-Gordon
Journal:  Mol Phys       Date:  2021-10-14       Impact factor: 1.937

5.  Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives.

Authors:  Michihisa Ueda; Kjell Jorner; Young Mo Sung; Tadashi Mori; Qi Xiao; Dongho Kim; Henrik Ottosson; Takuzo Aida; Yoshimitsu Itoh
Journal:  Nat Commun       Date:  2017-08-24       Impact factor: 14.919

6.  Why Aromaticity Is a Suspicious Concept? Why?

Authors:  Miquel Solà
Journal:  Front Chem       Date:  2017-03-24       Impact factor: 5.221

7.  "Bottled" spiro-doubly aromatic trinuclear [Pd2Ru]+ complexes.

Authors:  Maksim Kulichenko; Nikita Fedik; Anna Monfredini; Alvaro Muñoz-Castro; Davide Balestri; Alexander I Boldyrev; Giovanni Maestri
Journal:  Chem Sci       Date:  2020-10-23       Impact factor: 9.825

8.  Anomalous effect of non-alternant hydrocarbons on carbocation and carbanion electronic configurations.

Authors:  Logan J Fischer; Andrew S Dutton; Arthur H Winter
Journal:  Chem Sci       Date:  2017-05-04       Impact factor: 9.825

9.  Electronic and magnetic properties of the [Ni(salophen)]: An experimental and DFT study.

Authors:  Rodrigo A Mendes; José Carlos Germino; Bruno R Fazolo; Ericson H N S Thaines; Franklin Ferraro; Anderson M Santana; Romildo J Ramos; Gabriel L C de Souza; Renato G Freitas; Pedro A M Vazquez; Cristina A Barboza
Journal:  J Adv Res       Date:  2017-10-16       Impact factor: 10.479

10.  Structure-Property Relationships in Unsymmetric Bis(antiaromatics): Who Wins the Battle between Pentalene and Benzocyclobutadiene?†.

Authors:  Péter J Mayer; Ouissam El Bakouri; Tamás Holczbauer; Gergely F Samu; Csaba Janáky; Henrik Ottosson; Gábor London
Journal:  J Org Chem       Date:  2020-03-30       Impact factor: 4.354

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