| Literature DB >> 26035213 |
Abstract
We show that, by properly adopting the notion of temperature-dependent energy levels, the standard tools of differential thermodynamics can be used for a consistent thermostatistical description irrespective of system size. In this framework the paradigmatic (yet not always descriptive) large-system limit is no longer a necessary assumption for differential thermodynamics. We present a generalized relation between temperature and internal energy which extends thermodynamics all the way to isolated quantum systems.Year: 2015 PMID: 26035213 DOI: 10.1039/c5cp02332g
Source DB: PubMed Journal: Phys Chem Chem Phys ISSN: 1463-9076 Impact factor: 3.676