Literature DB >> 26035213

Temperature-dependent energy levels and size-independent thermodynamics.

Rodrigo de Miguel1.   

Abstract

We show that, by properly adopting the notion of temperature-dependent energy levels, the standard tools of differential thermodynamics can be used for a consistent thermostatistical description irrespective of system size. In this framework the paradigmatic (yet not always descriptive) large-system limit is no longer a necessary assumption for differential thermodynamics. We present a generalized relation between temperature and internal energy which extends thermodynamics all the way to isolated quantum systems.

Year:  2015        PMID: 26035213     DOI: 10.1039/c5cp02332g

Source DB:  PubMed          Journal:  Phys Chem Chem Phys        ISSN: 1463-9076            Impact factor:   3.676


  1 in total

1.  Heat capacities of thermally manipulated mechanical oscillator at strong coupling.

Authors:  Michal Kolář; Artem Ryabov; Radim Filip
Journal:  Sci Rep       Date:  2019-07-26       Impact factor: 4.379

  1 in total

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