Literature DB >> 26024202

Shape of dynamical heterogeneities and fractional Stokes-Einstein and Stokes-Einstein-Debye relations in quasi-two-dimensional suspensions of colloidal ellipsoids.

Chandan K Mishra1, Rajesh Ganapathy2.   

Abstract

We examine the influence of the shape of dynamical heterogeneities on the Stokes-Einstein (SE) and Stokes-Einstein-Debye (SED) relations in quasi-two-dimensional suspensions of colloidal ellipsoids. For ellipsoids with repulsive interactions, both SE and SED relations are violated at all area fractions. On approaching the glass transition, however, the extent to which this violation occurs changes beyond a crossover area fraction. Quite remarkably, we find that it is not just the presence of dynamical heterogeneities but their change in the shape from stringlike to compact that coincides with this crossover. On introducing a suitable short-range depletion attraction between the ellipsoids, associated with the lack of morphological evolution of dynamical heterogeneities, the extent to which the SE and SED relations are violated remains unchanged even for deep supercooling.

Year:  2015        PMID: 26024202     DOI: 10.1103/PhysRevLett.114.198302

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  3 in total

1.  Long-wavelength fluctuations and anomalous dynamics in 2-dimensional liquids.

Authors:  Yan-Wei Li; Chandan K Mishra; Zhao-Yan Sun; Kun Zhao; Thomas G Mason; Rajesh Ganapathy; Massimo Pica Ciamarra
Journal:  Proc Natl Acad Sci U S A       Date:  2019-10-28       Impact factor: 11.205

2.  Measurements of growing surface tension of amorphous-amorphous interfaces on approaching the colloidal glass transition.

Authors:  Divya Ganapathi; K Hima Nagamanasa; A K Sood; Rajesh Ganapathy
Journal:  Nat Commun       Date:  2018-01-26       Impact factor: 14.919

3.  Formation of a transient amorphous solid in low density aqueous charged sphere suspensions.

Authors:  Ran Niu; Sabrina Heidt; Ramsia Sreij; Riande I Dekker; Maximilian Hofmann; Thomas Palberg
Journal:  Sci Rep       Date:  2017-12-06       Impact factor: 4.379

  3 in total

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