| Literature DB >> 26023883 |
Xing-Zhong Shu1,2, Son C Nguyen1, Ying He1, Fadekemi Oba1, Qiao Zhang1, Christian Canlas1, Gabor A Somorjai1, A Paul Alivisatos1, F Dean Toste1.
Abstract
An efficient method for the synthesis of heterogeneous gold catalysts has been developed. These catalysts were easily assembled from readily available silica materials and gold complexes. The heterogeneous catalysts exhibited superior reactivity in various reactions where protodeauration is the rate-limiting step. Dramatic enhancement in regio- and enantioselectivity was observed when compared to the homogeneous unsupported gold catalyst. The catalysts are easily recovered and recycled up to 11 times without loss of enantioselectivity.Entities:
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Year: 2015 PMID： 26023883 DOI： 10.1021/jacs.5b04294
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419