Literature DB >> 26015999

Direct accessibility of mixed-metal (III/II) acid sites through the rational synthesis of porous metal carboxylates.

S Wongsakulphasatch1, F Nouar, J Rodriguez, L Scott, C Le Guillouzer, T Devic, P Horcajada, J-M Grenèche, P L Llewellyn, A Vimont, G Clet, M Daturi, C Serre.   

Abstract

The scalable and environmentally-friendly synthesis of mixed Fe(III)/M(II) (M = Ni, Co, Mg) polycarboxylate porous MOFs based on the Secondary Building Unit approach is reported. A combination of in situ infrared spectroscopy, (57)Fe Mössbauer spectrometry and adsorption microcalorimetry confirms the direct accessibility of the iron(III) and metal(II) sites under low temperature activation conditions.

Entities:  

Year:  2015        PMID： 26015999     DOI： 10.1039/c5cc02550h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  The thermally induced decarboxylation mechanism of a mixed-oxidation state carboxylate-based iron metal-organic framework.

Authors:  Hannah F Drake; Gregory S Day; Shaik Waseem Vali; Zhifeng Xiao; Sayan Banerjee; Jialuo Li; Elizabeth A Joseph; Jason E Kuszynski; Zachary T Perry; Angelo Kirchon; Osman K Ozdemir; Paul A Lindahl; Hong-Cai Zhou
Journal:  Chem Commun (Camb)       Date:  2019-09-30       Impact factor: 6.222

Review 2.  Bimetallic metal-organic frameworks and their derivatives.

Authors:  Liyu Chen; Hao-Fan Wang; Caixia Li; Qiang Xu
Journal:  Chem Sci       Date:  2020-04-28       Impact factor: 9.825

Review 3.  Metal-organic and covalent organic frameworks as single-site catalysts.

Authors:  S M J Rogge; A Bavykina; J Hajek; H Garcia; A I Olivos-Suarez; A Sepúlveda-Escribano; A Vimont; G Clet; P Bazin; F Kapteijn; M Daturi; E V Ramos-Fernandez; F X Llabrés I Xamena; V Van Speybroeck; J Gascon
Journal:  Chem Soc Rev       Date:  2017-06-06       Impact factor: 54.564
  3 in total

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