Literature DB >> 26008633

What is the primary mover of water dynamics?

P Ben Ishai1, S R Tripathi, K Kawase, A Puzenko, Yu Feldman.   

Abstract

Even today, the H-bonded cluster structure of water still stands as a major point of debate in the science of liquids. Much of this discussion is devoted to understand its dynamic nature. This has a direct impact on deciphering the many anomalies of water such as its exceptional heat capacity. Of these properties, dielectric permittivity and relaxation are of particular interest. The argument rages over whether the almost Debye-like character of the dispersion is the result of the reorientation of an apparent dipole moment of the water cluster or simply the cumulative effect of single water molecule reorientation. Furthermore, like many glass formers, it has a high frequency excess wing that does not fit into the accepted models of a single relaxation time of the main peak. Herein, we present evidence that the microscopic origins of both the excess wing and the main relaxation process of pure water are the same. The origin of these two features is explored and we suggest a new paradigm for water relaxation based on the concept of a proton cascade leading to a cluster reorientation.

Entities:  

Year:  2015        PMID: 26008633     DOI: 10.1039/c5cp01871d

Source DB:  PubMed          Journal:  Phys Chem Chem Phys        ISSN: 1463-9076            Impact factor:   3.676


  3 in total

1.  Dynamics of hydration water in gelatin and hyaluronic acid hydrogels.

Authors:  Sotiria Kripotou; Konstantinos Zafeiris; Maria Culebras-Martínez; Gloria Gallego Ferrer; Apostolos Kyritsis
Journal:  Eur Phys J E Soft Matter       Date:  2019-08-27       Impact factor: 1.890

Review 2.  Continuous noninvasive glucose monitoring; water as a relevant marker of glucose uptake in vivo.

Authors:  Andreas Caduff; Paul Ben Ishai; Yuri Feldman
Journal:  Biophys Rev       Date:  2019-11-18

3.  Dielectric property measurement of human sweat using attenuated total reflection terahertz time domain spectroscopy.

Authors:  Kazuma Hashimoto; Paul Ben Ishai; Erik Bründermann; Saroj R Tripathi
Journal:  Biomed Opt Express       Date:  2022-08-04       Impact factor: 3.562

  3 in total

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