Literature DB >> 26000869

Oxalyl chloride as a practical carbon monoxide source for carbonylation reactions.

Steffen V F Hansen1, Trond Ulven1.   

Abstract

A method for generation of high-quality carbon monoxide by decomposition of oxalyl chloride in an aqueous hydroxide solution is described. The usefulness of the method is demonstrated in the synthesis of heterocycles and for hydroxy-, alkoxy-, amino-, and reductive carbonylation reactions, in several cases under milder conditions than previously reported.

Entities:  

Year:  2015        PMID： 26000869     DOI： 10.1021/acs.orglett.5b01252

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Adapting decarbonylation chemistry for the development of prodrugs capable of in vivo delivery of carbon monoxide utilizing sweeteners as carrier molecules.

Authors:  Ladie Kimberly De La Cruz; Xiaoxiao Yang; Anna Menshikh; Maya Brewer; Wen Lu; Minjia Wang; Siming Wang; Xingyue Ji; Alyssa Cachuela; Haichun Yang; David Gallo; Chalet Tan; Leo Otterbein; Mark de Caestecker; Binghe Wang
Journal:  Chem Sci       Date:  2021-07-01       Impact factor: 9.969

2.  Non-equivalence of Key Positively Charged Residues of the Free Fatty Acid 2 Receptor in the Recognition and Function of Agonist Versus Antagonist Ligands.

Authors:  Eugenia Sergeev; Anders Højgaard Hansen; Sunil K Pandey; Amanda E MacKenzie; Brian D Hudson; Trond Ulven; Graeme Milligan
Journal:  J Biol Chem       Date:  2015-10-29       Impact factor: 5.157

3.  Synthesis of 4H-Benzo[e][1,3]oxazin-4-ones by a Carbonylation-Cyclization Domino Reaction of ortho-Halophenols and Cyanamide.

Authors:  Linda Åkerbladh; Shiao Y Chow; Luke R Odell; Mats Larhed
Journal:  ChemistryOpen       Date:  2017-08-16       Impact factor: 2.911

Review 4.  Heterogeneous Phase Microwave-Assisted Reactions under CO₂ or CO Pressure.

Authors:  Emanuela Calcio Gaudino; Laura Rinaldi; Laura Rotolo; Diego Carnaroglio; Camillo Pirola; Giancarlo Cravotto
Journal:  Molecules       Date:  2016-02-24       Impact factor: 4.411
  4 in total

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