| Literature DB >> 25994329 |
Marc-André Courtemanche1, Alexander P Pulis, Étienne Rochette, Marc-André Légaré, Douglas W Stephan, Frédéric-Georges Fontaine.
Abstract
The FLP species 1-BR2-2-NMe2-C6H4 (R = 2,4,6-Me3C6H2, 2,4,5-Me3C6H2) reacts with H2 in sequential hydrogen activation and protodeborylation reactions to give (1-BH2-2-NMe2-C6H4)2. While reacts with H2/CO2 to give formyl, acetal and methoxy-derivatives, reacts with H2/CO2 to give C6H4(NMe2)(B(2,4,5-Me3C6H2)O)2CH2. The mechanism of CO2 reduction is considered.Entities:
Year: 2015 PMID： 25994329 DOI： 10.1039/c5cc03072b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222