Literature DB >> 25994112

Probing Cu(I) in homogeneous catalysis using high-energy-resolution fluorescence-detected X-ray absorption spectroscopy.

Richard C Walroth1, Jacob W H Uebler, Kyle M Lancaster.   

Abstract

Metal-to-ligand charge transfer excitations in Cu(I) X-ray absorption spectra are introduced as spectroscopic handles for the characterization of species in homogeneous catalytic reaction mixtures. Analysis is supported by correlation of a spectral library to calculations and to complementary spectroscopic parameters.

Entities:  

Mesh：

Substances：

Year:  2015        PMID： 25994112      PMCID： PMC4540364          DOI： 10.1039/c5cc01827g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  24 in total

1.  Single-reference ab initio methods for the calculation of excited states of large molecules.

Authors:  Andreas Dreuw; Martin Head-Gordon
Journal:  Chem Rev       Date:  2005-11       Impact factor: 60.622

2.  High-resolution molybdenum K-edge X-ray absorption spectroscopy analyzed with time-dependent density functional theory.

Authors:  Frederico A Lima; Ragnar Bjornsson; Thomas Weyhermüller; Perumalreddy Chandrasekaran; Pieter Glatzel; Frank Neese; Serena DeBeer
Journal:  Phys Chem Chem Phys       Date:  2013-12-28       Impact factor: 3.676

3.  Sustainable metal catalysis with iron: from rust to a rising star?

Authors:  Stephan Enthaler; Kathrin Junge; Matthias Beller
Journal:  Angew Chem Int Ed Engl       Date:  2008       Impact factor: 15.336

4.  Chemistry. Radical ligands confer nobility on base-metal catalysts.

Authors:  Paul J Chirik; Karl Wieghardt
Journal:  Science       Date:  2010-02-12       Impact factor: 47.728

5.  A new iron age.

Authors:  Carsten Bolm
Journal:  Nat Chem       Date:  2009-08       Impact factor: 24.427

6.  Identification of highly active Fe sites in (Ni,Fe)OOH for electrocatalytic water splitting.

Authors:  Daniel Friebel; Mary W Louie; Michal Bajdich; Kai E Sanwald; Yun Cai; Anna M Wise; Mu-Jeng Cheng; Dimosthenis Sokaras; Tsu-Chien Weng; Roberto Alonso-Mori; Ryan C Davis; John R Bargar; Jens K Nørskov; Anders Nilsson; Alexis T Bell
Journal:  J Am Chem Soc       Date:  2015-01-16       Impact factor: 15.419

7.  Experimental fingerprints for redox-active terpyridine in [Cr(tpy)2](PF6)n (n = 3-0), and the remarkable electronic structure of [Cr(tpy)2]1-.

Authors:  Christopher C Scarborough; Kyle M Lancaster; Serena DeBeer; Thomas Weyhermüller; Stephen Sproules; Karl Wieghardt
Journal:  Inorg Chem       Date:  2012-03-06       Impact factor: 5.165

8.  Selective catalytic reduction of NO over Fe-ZSM-5: mechanistic insights by operando HERFD-XANES and valence-to-core X-ray emission spectroscopy.

Authors:  Alexey Boubnov; Hudson W P Carvalho; Dmitry E Doronkin; Tobias Günter; Erik Gallo; Andrew J Atkins; Christoph R Jacob; Jan-Dierk Grunwaldt
Journal:  J Am Chem Soc       Date:  2014-09-04       Impact factor: 15.419

9.  Direct spectroscopic characterization of a transitory dirhodium donor-acceptor carbene complex.

Authors:  Katherine P Kornecki; John F Briones; Vyacheslav Boyarskikh; Felicia Fullilove; Jochen Autschbach; Kaitlin E Schrote; Kyle M Lancaster; Huw M L Davies; John F Berry
Journal:  Science       Date:  2013-09-12       Impact factor: 47.728

10.  Ligand-sensitive but not ligand-diagnostic: evaluating Cr valence-to-core X-ray emission spectroscopy as a probe of inner-sphere coordination.

Authors:  Samantha N MacMillan; Richard C Walroth; Demetra M Perry; Thorbjørn J Morsing; Kyle M Lancaster
Journal:  Inorg Chem       Date:  2014-12-15       Impact factor: 5.165
View more
  9 in total

1.  Electronic Structures and Reactivity Profiles of Aryl Nitrenoid-Bridged Dicopper Complexes.

Authors:  Kurtis M Carsch; James T Lukens; Ida M DiMucci; Diana A Iovan; Shao-Liang Zheng; Kyle M Lancaster; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2020-01-22       Impact factor: 15.419

2.  Synthesis of a copper-supported triplet nitrene complex pertinent to copper-catalyzed amination.

Authors:  Kurtis M Carsch; Ida M DiMucci; Diana A Iovan; Alex Li; Shao-Liang Zheng; Charles J Titus; Sang Jun Lee; Kent D Irwin; Dennis Nordlund; Kyle M Lancaster; Theodore A Betley
Journal:  Science       Date:  2019-09-13       Impact factor: 47.728

3.  Following a Silent Metal Ion: A Combined X-ray Absorption and Nuclear Magnetic Resonance Spectroscopic Study of the Zn2+ Cation Dissipative Translocation between Two Different Ligands.

Authors:  Federico Frateloreto; Francesco Tavani; Marika Di Berto Mancini; Daniele Del Giudice; Giorgio Capocasa; Isabelle Kieffer; Osvaldo Lanzalunga; Stefano Di Stefano; Paola D'Angelo
Journal:  J Phys Chem Lett       Date:  2022-06-13       Impact factor: 6.888

4.  The Myth of d8 Copper(III).

Authors:  Ida M DiMucci; James T Lukens; Sudipta Chatterjee; Kurtis M Carsch; Charles J Titus; Sang Jun Lee; Dennis Nordlund; Theodore A Betley; Samantha N MacMillan; Kyle M Lancaster
Journal:  J Am Chem Soc       Date:  2019-11-11       Impact factor: 15.419

5.  Structure, Spectroscopy, and Reactivity of a Mononuclear Copper Hydroxide Complex in Three Molecular Oxidation States.

Authors:  Tong Wu; Samantha N MacMillan; Khashayar Rajabimoghadam; Maxime A Siegler; Kyle M Lancaster; Isaac Garcia-Bosch
Journal:  J Am Chem Soc       Date:  2020-07-01       Impact factor: 15.419

6.  Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides.

Authors:  Conrad A P Goodwin; Benjamin L L Réant; Gianni F Vettese; Jon G C Kragskow; Marcus J Giansiracusa; Ida M DiMucci; Kyle M Lancaster; David P Mills; Stephen Sproules
Journal:  Inorg Chem       Date:  2020-05-18       Impact factor: 5.165

7.  Heteroleptic samarium(iii) halide complexes probed by fluorescence-detected L3-edge X-ray absorption spectroscopy.

Authors:  Conrad A P Goodwin; Benjamin L L Réant; Jon G C Kragskow; Ida M DiMucci; Kyle M Lancaster; David P Mills; Stephen Sproules
Journal:  Dalton Trans       Date:  2018-05-23       Impact factor: 4.390

8.  Scrutinizing metal-ligand covalency and redox non-innocence via nitrogen K-edge X-ray absorption spectroscopy.

Authors:  James T Lukens; Ida M DiMucci; Takashi Kurogi; Daniel J Mindiola; Kyle M Lancaster
Journal:  Chem Sci       Date:  2019-04-17       Impact factor: 9.825

9.  X-ray Absorption and Emission Spectroscopic Studies of [L2Fe2S2](n) Model Complexes: Implications for the Experimental Evaluation of Redox States in Iron-Sulfur Clusters.

Authors:  Joanna K Kowalska; Anselm W Hahn; Antonia Albers; Christine E Schiewer; Ragnar Bjornsson; Frederico A Lima; Franc Meyer; Serena DeBeer
Journal:  Inorg Chem       Date:  2016-04-20       Impact factor: 5.165
  9 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.