Literature DB >> 25992842

Direct synthesis of a {Co₆(III)Fe₆(III)} dodecanuclear complex, revealing an unprecedented molecular structure type.

Eduard N Chygorin1, Vladimir N Kokozay, Irina V Omelchenko, Oleg V Shishkin, Ján Titiš, Roman Boča, Dmytro S Nesterov.   

Abstract

A novel heterometallic Co6Fe6 Schiff base complex, possessing an unprecedented {M12(μ-X)22} branched structure (according to the search via the Cambridge Structural Database), has been prepared using the "direct synthesis" approach and characterized by single crystal X-ray diffraction and magnetometry.

Entities:  

Year:  2015        PMID: 25992842     DOI: 10.1039/c5dt01149c

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  1 in total

1.  Crystal structure of tetra-kis-(μ3-2-{[1,1-bis-(hy-droxy-meth-yl)-2-oxidoeth-yl]imino-meth-yl}-6-meth-oxy-phenolato)tetra-kis-[aqua-copper(II)]: a redetermination at 200 K.

Authors:  Elena A Buvaylo; Olga Yu Vassilyeva; Brian W Skelton
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-09-26
  1 in total

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