Literature DB >> 25978124

Synthesis of Luffarin L and 16-epi-Luffarin L Using a Temporary Silicon-Tethered Ring-Closing Metathesis Reaction.

Aitor Urosa1, Isidro S Marcos1, David Díez1, José M Padrón2, Pilar Basabe1.   

Abstract

The first synthesis of luffarin L (1) and 16-epi-luffarin L (2) by a silicon-tethered ring closing metathesis as a key step has been achieved. The stereochemistry and absolute configuration of the natural sesterterpenolide luffarin L (1) and a new route for the stereoselective synthesis of sesterterpenolides with a luffarane skeleton have been established.

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Year:  2015        PMID： 25978124     DOI： 10.1021/acs.joc.5b00876

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  2 in total

1.  Ring-closing metathesis as key step in the synthesis of Luffarin I, 16-epi-Luffarin I and Luffarin A.

Authors:  Aitor Urosa; Isidro S Marcos; David Díez; Gabriela B Plata; José M Padrón; Pilar Basabe
Journal:  Mol Divers       Date:  2015-10-20       Impact factor: 2.943

2.  Phosphate Tether-Mediated Ring-Closing Metathesis for the Generation of P-Stereogenic, Z-Configured Bicyclo[7.3.1]- and Bicyclo[8.3.1]phosphates.

Authors:  Jana L Markley; Soma Maitra; Paul R Hanson
Journal:  J Org Chem       Date:  2016-01-21       Impact factor: 4.354
  2 in total

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