Literature DB >> 25978094

Ipso-Borylation of Aryl Ethers via Ni-Catalyzed C-OMe Cleavage.

Cayetana Zarate1, Rubén Manzano1, Ruben Martin1,2.   

Abstract

A Ni-catalyzed ipso-borylation of aryl ethers via C(sp(2))-OMe and C(sp(3))-OMe cleavage is described. The transformation is characterized by its wide substrate scope under mild conditions and an exquisite divergence in site selectivity that can be easily switched by selecting the appropriate boron reagent.

Entities:  

Year:  2015        PMID: 25978094     DOI: 10.1021/jacs.5b03955

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  16 in total

1.  Cross-Coupling and Related Reactions: Connecting Past Success to the Development of New Reactions for the Future.

Authors:  Louis-Charles Campeau; Nilay Hazari
Journal:  Organometallics       Date:  2018-11-27       Impact factor: 3.876

2.  Mechanism and Origins of Ligand-Controlled Stereoselectivity of Ni-Catalyzed Suzuki-Miyaura Coupling with Benzylic Esters: A Computational Study.

Authors:  Shuo-Qing Zhang; Buck L H Taylor; Chong-Lei Ji; Yuan Gao; Michael R Harris; Luke E Hanna; Elizabeth R Jarvo; K N Houk; Xin Hong
Journal:  J Am Chem Soc       Date:  2017-09-07       Impact factor: 15.419

3.  Manual and automated Cu-mediated radiosynthesis of the PARP inhibitor [18F]olaparib.

Authors:  Florian Guibbal; Patrick G Isenegger; Thomas C Wilson; Anna Pacelli; Damien Mahaut; Jeroen B I Sap; Nicholas J Taylor; Stefan Verhoog; Sean Preshlock; Rebekka Hueting; Bart Cornelissen; Véronique Gouverneur
Journal:  Nat Protoc       Date:  2020-02-28       Impact factor: 13.491

4.  Nickel-Catalyzed Borylation of Benzylic Ammonium Salts: Stereospecific Synthesis of Enantioenriched Benzylic Boronates.

Authors:  Corey H Basch; Kelsey M Cobb; Mary P Watson
Journal:  Org Lett       Date:  2015-12-17       Impact factor: 6.005

5.  Visible Light-Induced Borylation of C-O, C-N, and C-X Bonds.

Authors:  Shengfei Jin; Hang T Dang; Graham C Haug; Ru He; Viet D Nguyen; Vu T Nguyen; Hadi D Arman; Kirk S Schanze; Oleg V Larionov
Journal:  J Am Chem Soc       Date:  2020-01-10       Impact factor: 15.419

6.  Selective Benzylic CH-Borylations by Tandem Cobalt Catalysis.

Authors:  Pradip Ghosh; Roland Schoch; Matthias Bauer; Axel Jacobi von Wangelin
Journal:  Angew Chem Int Ed Engl       Date:  2021-11-22       Impact factor: 16.823

7.  Rhodium-Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids.

Authors:  Hidenori Ochiai; Yuta Uetake; Takashi Niwa; Takamitsu Hosoya
Journal:  Angew Chem Int Ed Engl       Date:  2017-01-26       Impact factor: 15.336

8.  Overcoming the Naphthyl Requirement in Stereospecific Cross-Couplings to Form Quaternary Stereocenters.

Authors:  Jianyu Xu; Olivia P Bercher; Mary P Watson
Journal:  J Am Chem Soc       Date:  2021-06-01       Impact factor: 16.383

9.  Oxidative addition of carbon-fluorine and carbon-oxygen bonds to Al(I).

Authors:  Mark R Crimmin; Michael J Butler; Andrew J P White
Journal:  Chem Commun (Camb)       Date:  2015-09-21       Impact factor: 6.222

10.  C-H arylation and alkenylation of imidazoles by nickel catalysis: solvent-accelerated imidazole C-H activation.

Authors:  Kei Muto; Taito Hatakeyama; Junichiro Yamaguchi; Kenichiro Itami
Journal:  Chem Sci       Date:  2015-09-08       Impact factor: 9.825

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