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Literature DB >> 25974714

Frustrated Lewis pair chemistry: development and perspectives.

Abstract

Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in solution that are deterred from strong adduct formation by steric and/or electronic factors. This opens pathways to novel cooperative reactions with added substrates. Small-molecule binding and activation by FLPs has led to the discovery of a variety of new reactions through unprecedented pathways. Hydrogen activation and subsequent manipulation in metal-free catalytic hydrogenations is a frequently observed feature of many FLPs. The current state of this young but rapidly expanding field is outlined in this Review and the future directions for its broadening sphere of impact are considered.

Entities: Chemical

Keywords: cooperative reactions; frustrated Lewis pairs; metal-free hydrogenation; small-molecule activation

Year: 2015 PMID： 25974714 DOI： 10.1002/anie.201409800

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

118 in total

1. B(C₆F₅)₃-Catalyzed Direct C3 Alkylation of Indoles and Oxindoles.

Authors: Shyam Basak; Ana Alvarez-Montoya; Laura Winfrey; Rebecca L Melen; Louis C Morrill; Alexander P Pulis
Journal: ACS Catal Date: 2020-04-09 Impact factor: 13.084

Review 2. Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides.

Authors: David Schilter; James M Camara; Mioy T Huynh; Sharon Hammes-Schiffer; Thomas B Rauchfuss
Journal: Chem Rev Date: 2016-06-29 Impact factor: 60.622

3. Chemoselective Lewis pair polymerization of renewable multivinyl-functionalized γ-butyrolactones.

Authors: Ravikumar R Gowda; Eugene Y-X Chen
Journal: Philos Trans A Math Phys Eng Sci Date: 2017-08-28 Impact factor: 4.226

4. Halogenated triphenylgallium and -indium in frustrated Lewis pair activations and hydrogenation catalysis.

Authors: Maotong Xu; Josephine Possart; Alexander E Waked; Julie Roy; Werner Uhl; Douglas W Stephan
Journal: Philos Trans A Math Phys Eng Sci Date: 2017-08-28 Impact factor: 4.226

5. A DFT study of hydrogen and methane activation by B(C₆F₅)₃/P(t-Bu)₃ and Al(C₆F₅)₃/P(t-Bu)₃ frustrated Lewis pairs.

Authors: Nery Villegas-Escobar; Alejandro Toro-Labbé; Marcos Becerra; Misael Real-Enriquez; Jose R Mora; Luis Rincon
Journal: J Mol Model Date: 2017-07-21 Impact factor: 1.810

6. Enantioselective Conia-Ene-Type Cyclizations of Alkynyl Ketones through Cooperative Action of B(C₆F₅)₃, N-Alkylamine and a Zn-Based Catalyst.

Authors: Min Cao; Ahmet Yesilcimen; Masayuki Wasa
Journal: J Am Chem Soc Date: 2019-02-27 Impact factor: 15.419

10. Direct Conversion of N-Alkylamines to N-Propargylamines through C-H Activation Promoted by Lewis Acid/Organocopper Catalysis: Application to Late-Stage Functionalization of Bioactive Molecules.

Authors: Jessica Z Chan; Ahmet Yesilcimen; Min Cao; Yuyang Zhang; Bochao Zhang; Masayuki Wasa
Journal: J Am Chem Soc Date: 2020-09-11 Impact factor: 15.419