Literature DB >> 25972044

Copper(I)-photocatalyzed trifluoromethylation of alkenes.

R Beniazza1, F Molton, C Duboc, A Tron, N D McClenaghan, D Lastécouères, J-M Vincent.   

Abstract

Using the photoreducible Cu(II) precatalyst 2, trifluoromethylation reactions of alkenes are conducted effectively at low copper loading (0.1-0.5 mol%) on exposing the reaction mixture to sunlight/ambient light.

Entities:  

Year:  2015        PMID： 25972044     DOI： 10.1039/c5cc01923k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Transforming Olefins into γ,δ-Unsaturated Nitriles through Copper Catalysis.

Authors:  Xuesong Wu; Jan Riedel; Vy M Dong
Journal:  Angew Chem Int Ed Engl       Date:  2017-08-10       Impact factor: 15.336

2.  Trifluoroethoxy-Coated Subphthalocyanine affects Trifluoromethylation of Alkenes and Alkynes even under Low-Energy Red-Light Irradiation.

Authors:  Kohei Matsuzaki; Tomoya Hiromura; Etsuko Tokunaga; Norio Shibata
Journal:  ChemistryOpen       Date:  2017-02-21       Impact factor: 2.911

3.  Effective ascorbate-free and photolatent click reactions in water using a photoreducible copper(II)-ethylenediamine precatalyst.

Authors:  Redouane Beniazza; Natalia Bayo; Florian Molton; Carole Duboc; Stéphane Massip; Nathan McClenaghan; Dominique Lastécouères; Jean-Marc Vincent
Journal:  Beilstein J Org Chem       Date:  2015-10-21       Impact factor: 2.883

4.  Redox-ligand sustains controlled generation of CF3 radicals by well-defined copper complex.

Authors:  Jérémy Jacquet; Sébastien Blanchard; Etienne Derat; Marine Desage-El Murr; Louis Fensterbank
Journal:  Chem Sci       Date:  2015-12-03       Impact factor: 9.825
  4 in total

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