Literature DB >> 25955879

Difunctionalization of Alkenes via the Visible-Light-Induced Trifluoromethylarylation/1,4-Aryl Shift/Desulfonylation Cascade Reactions.

Lewei Zheng1, Chao Yang1, ZhaoZhong Xu1, Fei Gao1, Wujiong Xia1.   

Abstract

A novel visible-light-induced trifluoromethylarylation/1,4-aryl shift/desulfonylation cascade reaction using CF3SO2Cl as CF3 source was described. The protocol provides an efficient approach for the synthesis of α-aryl-β-trifluoromethyl amides and/or CF3-containing oxindoles as well as the isoquinolinediones under benign conditions.

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Year:  2015        PMID: 25955879     DOI: 10.1021/acs.joc.5b00677

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  5 in total

Review 1.  Aryl Transfer Strategies Mediated by Photoinduced Electron Transfer.

Authors:  Anthony R Allen; Efrey A Noten; Corey R J Stephenson
Journal:  Chem Rev       Date:  2021-10-21       Impact factor: 72.087

2.  Alkene 1,2-Difunctionalization by Radical Alkenyl Migration.

Authors:  Xinjun Tang; Armido Studer
Journal:  Angew Chem Int Ed Engl       Date:  2017-12-14       Impact factor: 15.336

3.  α-Perfluoroalkyl-β-alkynylation of alkenes via radical alkynyl migration.

Authors:  Xinjun Tang; Armido Studer
Journal:  Chem Sci       Date:  2017-08-04       Impact factor: 9.825

4.  Synthesis of trifluoromethyl-containing isoindolinones from tertiary enamides via a cascade radical addition and cyclization process.

Authors:  Hui Yu; Mingdong Jiao; Xiaowei Fang; Pengfei Xuan
Journal:  RSC Adv       Date:  2018-07-03       Impact factor: 3.361

5.  CF3SO2X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation and chlorination. Part 2: Use of CF3SO2Cl.

Authors:  Hélène Chachignon; Hélène Guyon; Dominique Cahard
Journal:  Beilstein J Org Chem       Date:  2017-12-19       Impact factor: 2.883

  5 in total

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