Literature DB >> 25952320

Efficient masking of corrosion and fission products such as Ni(II) and Pd(II) in the presence of the minor actinide Am(III) using hydrophilic anionic or cationic bis-triazines.

Frank W Lewis1, Laurence M Harwood, Michael J Hudson, Udo Müllich, Andreas Geist.   

Abstract

Water soluble anionic and cationic bis-triazine ligands are able to suppress (mask) the extraction of corrosion and fission products such as Ni(II) and Pd(II) that are found in PUREX raffinates. Thus it is possible to separate these elements from the minor actinide Am(III). Although some masking agents have previously been developed that retard the extraction of Pd(II), this is the first time a masking agent has been developed for Ni(II).

Entities:  

Year:  2015        PMID: 25952320     DOI: 10.1039/c5cc02336j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Hydrophilic sulfonated bis-1,2,4-triazine ligands are highly effective reagents for separating actinides(iii) from lanthanides(iii) via selective formation of aqueous actinide complexes.

Authors:  Frank W Lewis; Laurence M Harwood; Michael J Hudson; Andreas Geist; Valery N Kozhevnikov; Petr Distler; Jan John
Journal:  Chem Sci       Date:  2015-05-28       Impact factor: 9.825

  1 in total

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