| Literature DB >> 25951520 |
Sandro Gennen1, Margot Alves2, Raphaël Méreau2, Thierry Tassaing2, Bernard Gilbert3, Christophe Detrembleur4, Christine Jerome5, Bruno Grignard1.
Abstract
The addition of fluorinated alcohols to onium salts provides highly efficient organocatalysts for the chemical fixation of CO2 into epoxides under mild experimental conditions. The combination of online kinetic studies, NMR titrations and DFT calculations allows understanding this synergistic effect that provides an active organocatalyst for CO2 /epoxides coupling.Entities:
Keywords: carbon dioxide; carbonates; epoxides; fluor; organocatalysis
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Year: 2015 PMID： 25951520 DOI： 10.1002/cssc.201500103
Source DB: PubMed Journal: ChemSusChem ISSN： 1864-5631 Impact factor: 8.928