Literature DB >> 25951192

Instantaneous hydrolysis of nerve-agent simulants with a six-connected zirconium-based metal-organic framework.

Su-Young Moon1, Yangyang Liu1, Joseph T Hupp2, Omar K Farha3,4.   

Abstract

A nerve-agent simulant based on a phosphate ester is hydrolyzed using a MOF-based catalyst. Suspensions of MOF-808 (6-connected), a material featuring 6-connected zirconium nodes, display the highest hydrolysis rates among all MOFs that have been reported to date. A plug-flow reactor was also prepared with MOF-808 (6-connected) as the active layer. Deployed in a simple filtration scheme, the reactor displayed high hydrolysis efficiency and reusability.
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  MOF plug-flow reactor; heterogeneous catalysis; hydrolysis; metal-organic frameworks; nerve agents

Year:  2015        PMID： 25951192     DOI： 10.1002/anie.201502155

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  15 in total

1.  Efficient and selective oxidation of sulfur mustard using singlet oxygen generated by a pyrene-based metal-organic framework.

Authors:  Yangyang Liu; Cassandra T Buru; Ashlee J Howarth; John J Mahle; James H Buchanan; Jared B DeCoste; Joseph T Hupp; Omar K Farha
Journal:  J Mater Chem A Mater       Date:  2016-08-23

Review 2.  Metal-organic and covalent organic frameworks as single-site catalysts.

Authors:  S M J Rogge; A Bavykina; J Hajek; H Garcia; A I Olivos-Suarez; A Sepúlveda-Escribano; A Vimont; G Clet; P Bazin; F Kapteijn; M Daturi; E V Ramos-Fernandez; F X Llabrés I Xamena; V Van Speybroeck; J Gascon
Journal:  Chem Soc Rev       Date:  2017-06-06       Impact factor: 54.564

3.  Mechanochemical and solvent-free assembly of zirconium-based metal-organic frameworks.

Authors:  Krunoslav Užarević; Timothy C Wang; Su-Young Moon; Athena M Fidelli; Joseph T Hupp; Omar K Farha; Tomislav Friščić
Journal:  Chem Commun (Camb)       Date:  2016-02-04       Impact factor: 6.222

4.  Atomic-Level Structural Dynamics of Polyoxoniobates during DMMP Decomposition.

Authors:  Qi Wang; Robert C Chapleski; Anna M Plonka; Wesley O Gordon; Weiwei Guo; Thuy-Duong Nguyen-Phan; Conor H Sharp; Nebojsa S Marinkovic; Sanjaya D Senanayake; John R Morris; Craig L Hill; Diego Troya; Anatoly I Frenkel
Journal:  Sci Rep       Date:  2017-04-10       Impact factor: 4.379

Review 5.  Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber.

Authors:  Cristina Mottillo; Tomislav Friščić
Journal:  Molecules       Date:  2017-01-17       Impact factor: 4.411

6.  Coordination-Cage-Catalysed Hydrolysis of Organophosphates: Cavity- or Surface-Based?

Authors:  Christopher G P Taylor; Alexander J Metherell; Stephen P Argent; Fatma M Ashour; Nicholas H Williams; Michael D Ward
Journal:  Chemistry       Date:  2020-02-06       Impact factor: 5.236

7.  Tuning the Properties of MOF-808 via Defect Engineering and Metal Nanoparticle Encapsulation.

Authors:  Rifan Hardian; Stefano Dissegna; Aladin Ullrich; Philip L Llewellyn; Marie-Vanessa Coulet; Roland A Fischer
Journal:  Chemistry       Date:  2021-03-16       Impact factor: 5.236

8.  Rapid, Biomimetic Degradation of a Nerve Agent Simulant by Incorporating Imidazole Bases into a Metal-Organic Framework.

Authors:  Hong-Bin Luo; Anthony J Castro; Megan C Wasson; Willmer Flores; Omar K Farha; Yangyang Liu
Journal:  ACS Catal       Date:  2021-01-14       Impact factor: 13.084

Review 9.  Molecular Recognition of Nerve Agents and Their Organophosphorus Surrogates: Toward Supramolecular Scavengers and Catalysts.

Authors:  Tyler J Finnegan; Vageesha W Liyana Gunawardana; Jovica D Badjić
Journal:  Chemistry       Date:  2021-08-10       Impact factor: 5.020

Review 10.  Stable Metal-Organic Frameworks with Group 4 Metals: Current Status and Trends.

Authors:  Shuai Yuan; Jun-Sheng Qin; Christina T Lollar; Hong-Cai Zhou
Journal:  ACS Cent Sci       Date:  2018-03-26       Impact factor: 14.553
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