Literature DB >> 25945401

Cobalt(III)-Catalyzed C-H Bond Amidation with Isocyanates.

Joshua R Hummel1, Jonathan A Ellman1.   

Abstract

The first examples of cobalt(III)-catalyzed C-H bond addition to isocyanates are described, providing a convergent strategy for arene and heteroarene amidation. Using a robust air- and moisture-stable catalyst, this transformation demonstrates a broad isocyanate scope and good functional-group compatibility and has been performed on gram scale.

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Year:  2015        PMID： 25945401      PMCID： PMC4460580          DOI： 10.1021/acs.orglett.5b00910

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  59 in total

1.  From C(sp2)-H to C(sp3)-H: systematic studies on transition metal-catalyzed oxidative C-C formation.

Authors:  Bi-Jie Li; Zhang-Jie Shi
Journal:  Chem Soc Rev       Date:  2012-07-10       Impact factor: 54.564

2.  Oxidative coupling of aromatic substrates with alkynes and alkenes under rhodium catalysis.

Authors:  Tetsuya Satoh; Masahiro Miura
Journal:  Chemistry       Date:  2010-10-04       Impact factor: 5.236

3.  Rhodium-catalyzed direct addition of aryl C-H bonds to N-sulfonyl aldimines.

Authors:  Yang Li; Bi-Jie Li; Wen-Hua Wang; Wei-Ping Huang; Xi-Sha Zhang; Kang Chen; Zhang-Jie Shi
Journal:  Angew Chem Int Ed Engl       Date:  2011-01-26       Impact factor: 15.336

4.  Ruthenium(II)-catalyzed C-H bond activation and functionalization.

Authors:  Percia Beatrice Arockiam; Christian Bruneau; Pierre H Dixneuf
Journal:  Chem Rev       Date:  2012-08-31       Impact factor: 60.622

5.  Expedient synthesis of N-acyl anthranilamides and β-enamine amides by the Rh(III)-catalyzed amidation of aryl and vinyl C-H bonds with isocyanates.

Authors:  Kevin D Hesp; Robert G Bergman; Jonathan A Ellman
Journal:  J Am Chem Soc       Date:  2011-07-08       Impact factor: 15.419

6.  Rhodium-catalyzed oxidative ortho-acylation of benzamides with aldehydes: direct functionalization of the sp2 C-H bond.

Authors:  Jihye Park; Eonjeong Park; Aejin Kim; Youngil Lee; Ki-Whan Chi; Jong Hwan Kwak; Young Hoon Jung; In Su Kim
Journal:  Org Lett       Date:  2011-07-27       Impact factor: 6.005

7.  Cobalt-catalyzed C-H cyanation of (hetero)arenes and 6-arylpurines with N-cyanosuccinimide as a new cyanating agent.

Authors:  Amit B Pawar; Sukbok Chang
Journal:  Org Lett       Date:  2015-01-20       Impact factor: 6.005

8.  Low-valent cobalt catalysis: new opportunities for C-H functionalization.

Authors:  Ke Gao; Naohiko Yoshikai
Journal:  Acc Chem Res       Date:  2014-02-27       Impact factor: 22.384

Review 9.  C-H bond functionalization: emerging synthetic tools for natural products and pharmaceuticals.

Authors:  Junichiro Yamaguchi; Atsushi D Yamaguchi; Kenichiro Itami
Journal:  Angew Chem Int Ed Engl       Date:  2012-08-06       Impact factor: 15.336

10.  Rhenium-catalyzed synthesis of 3-imino-1-isoindolinones by C-H bond activation: application to the synthesis of polyimide derivatives.

Authors:  Shunsuke Sueki; Yuanfang Guo; Motomu Kanai; Yoichiro Kuninobu
Journal:  Angew Chem Int Ed Engl       Date:  2013-09-13       Impact factor: 15.336
View more
  8 in total

1.  Highly Stereoselective Cobalt(III)-Catalyzed Three-Component C-H Bond Addition Cascade.

Authors:  Jeffrey A Boerth; Joshua R Hummel; Jonathan A Ellman
Journal:  Angew Chem Int Ed Engl       Date:  2016-06-15       Impact factor: 15.336

2.  Transition-Metal-Catalyzed C-H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds.

Authors:  Joshua R Hummel; Jeffrey A Boerth; Jonathan A Ellman
Journal:  Chem Rev       Date:  2016-12-12       Impact factor: 60.622

3.  RhodiumIII-catalyzed remote difunctionalization of arenes assisted by a relay directing group.

Authors:  Lincong Sun; Yuyao Zhao; Bingxian Liu; Junbiao Chang; Xingwei Li
Journal:  Chem Sci       Date:  2022-05-30       Impact factor: 9.969

4.  Efficient Benzimidazolidinone Synthesis via Rhodium-Catalyzed Double-Decarbonylative C-C Activation/Cycloaddition between Isatins and Isocyanates.

Authors:  Rong Zeng; Peng-Hao Chen; Guangbin Dong
Journal:  ACS Catal       Date:  2015-12-30       Impact factor: 13.084

Review 5.  A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Authors:  Carlo Sambiagio; David Schönbauer; Remi Blieck; Toan Dao-Huy; Gerit Pototschnig; Patricia Schaaf; Thomas Wiesinger; Muhammad Farooq Zia; Joanna Wencel-Delord; Tatiana Besset; Bert U W Maes; Michael Schnürch
Journal:  Chem Soc Rev       Date:  2018-08-28       Impact factor: 54.564

6.  Ru(II)-Catalyzed Regioselective C-N Bond Formation on Benzothiazoles Employing Acyl Azide as an Amidating Agent.

Authors:  Stephy Elza John; Darshana Bora; Vivek Dhiman; Ramya Tokala; Gananadhamu Samanthula; Nagula Shankaraiah
Journal:  ACS Omega       Date:  2021-12-27

7.  Cobalt(iii)-catalyzed site-selective C-H amidation of pyridones and isoquinolones.

Authors:  Feng Gao; Xu Han; Chunpu Li; Lingjun Liu; Zhanqing Cong; Hong Liu
Journal:  RSC Adv       Date:  2018-09-21       Impact factor: 3.361

Review 8.  Hydroarylations by cobalt-catalyzed C-H activation.

Authors:  Rajagopal Santhoshkumar; Chien-Hong Cheng
Journal:  Beilstein J Org Chem       Date:  2018-08-29       Impact factor: 2.883
  8 in total

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