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Literature DB >> 25942045

Nickel-catalyzed direct amination of arenes with alkylamines.

Qiangqiang Yan, Zhengkai Chen, Wenlong Yu, Hong Yin, Zhanxiang Liu, Yuhong Zhang¹.

Abstract

The efficient nickel-catalyzed direct amination of arenes with simple alkylamines has been achieved with the assistance of a bidentate directing group through sp(2) C-H bond functionalization. Preliminary mechanistic investigations indicate that the reaction probably proceeds through a Ni(I)/Ni(III) catalytic pathway.

Entities: Chemical

Year: 2015 PMID： 25942045 DOI： 10.1021/acs.orglett.5b00990

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

8 in total

1. Ir-Catalyzed Intermolecular Branch-Selective Allylic C-H Amidation of Unactivated Terminal Olefins.

Authors: Honghui Lei; Tomislav Rovis
Journal: J Am Chem Soc Date: 2019-02-04 Impact factor: 15.419

2. A General Method for Aminoquinoline-Directed, Copper-Catalyzed sp(2) C-H Bond Amination.

Authors: James Roane; Olafs Daugulis
Journal: J Am Chem Soc Date: 2016-03-18 Impact factor: 15.419

Review 3. A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Authors: Carlo Sambiagio; David Schönbauer; Remi Blieck; Toan Dao-Huy; Gerit Pototschnig; Patricia Schaaf; Thomas Wiesinger; Muhammad Farooq Zia; Joanna Wencel-Delord; Tatiana Besset; Bert U W Maes; Michael Schnürch
Journal: Chem Soc Rev Date: 2018-08-28 Impact factor: 54.564

Nickel-catalyzed direct amination of arenes with alkylamines.

1. Ir-Catalyzed Intermolecular Branch-Selective Allylic C-H Amidation of Unactivated Terminal Olefins.

2. A General Method for Aminoquinoline-Directed, Copper-Catalyzed sp(2) C-H Bond Amination.

Review 3. A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

4. Intermolecular Aryl C-H Amination through Sequential Iron and Copper Catalysis.

5. Radical-mediated direct C-H amination of arenes with secondary amines.

6. Nickel(ii)-catalyzed tandem C(sp²)-H bond activation and annulation of arenes with gem-dibromoalkenes.

7. Nickel-catalyzed C-H/N-H annulation of aromatic amides with alkynes in the absence of a specific chelation system.

8. Synthesis of Densely Functionalized Pyrimidouracils by Nickel(II)-Catalyzed Isocyanide Insertion.