| Literature DB >> 25940751 |
Seungbeom Lee1, Hongchan An, Dong-Jo Chang, Jaebong Jang, Kyeojin Kim, Jaehoon Sim, Jeeyeon Lee, Young-Ger Suh.
Abstract
Enantioselective synthesis of (-)-deguelin was accomplished via an iterative pyran-ring formation approach. The key features involve the anionic addition of a chromene unit to aryloxy alkyl aldehyde for the double cyclization precursor and iterative pyran ring formation by Pd-catalyzed O-arylation and C-arylation, respectively.Entities:
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Year: 2015 PMID： 25940751 DOI： 10.1039/c5cc02215k
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222