Literature DB >> 25925137

Rhenium-catalyzed dehydrogenative olefination of C(sp(3))-H bonds with hypervalent iodine(III) reagents.

Haidong Gu1, Congyang Wang.   

Abstract

A dehydrogenative olefination of C(sp(3))-H bonds is disclosed here, by merging rhenium catalysis with an alanine-derived hypervalent iodine(III) reagent. Thus, cyclic and acyclic ethers, toluene derivatives, cycloalkanes, and nitriles are all successfully alkenylated in a regio- and stereoselective manner.

Entities:  

Year:  2015        PMID： 25925137     DOI： 10.1039/c5ob00619h

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  4 in total

1.  Preparation, structure, and reactivity of bicyclic benziodazole: a new hypervalent iodine heterocycle.

Authors:  Akira Yoshimura; Michael T Shea; Cody L Makitalo; Melissa E Jarvi; Gregory T Rohde; Akio Saito; Mekhman S Yusubov; Viktor V Zhdankin
Journal:  Beilstein J Org Chem       Date:  2018-05-08       Impact factor: 2.883

2.  Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes.

Authors:  Hui Cao; Yulong Kuang; Xiangcheng Shi; Koi Lin Wong; Boon Beng Tan; Jeric Mun Chung Kwan; Xiaogang Liu; Jie Wu
Journal:  Nat Commun       Date:  2020-04-23       Impact factor: 14.919

3.  Convenient Synthesis of Benziodazolone: New Reagents for Direct Esterification of Alcohols and Amidation of Amines.

Authors:  Michael T Shea; Gregory T Rohde; Yulia A Vlasenko; Pavel S Postnikov; Mekhman S Yusubov; Viktor V Zhdankin; Akio Saito; Akira Yoshimura
Journal:  Molecules       Date:  2021-12-03       Impact factor: 4.411

4.  Cascade alkylarylation of substituted N-allylbenzamides for the construction of dihydroisoquinolin-1(2H)-ones and isoquinoline-1,3(2H,4H)-diones.

Authors:  Ping Qian; Bingnan Du; Wei Jiao; Haibo Mei; Jianlin Han; Yi Pan
Journal:  Beilstein J Org Chem       Date:  2016-02-17       Impact factor: 2.883
  4 in total

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