Literature DB >> 25904305

Contribution to the benchmark for ternary mixtures: Measurement of the Soret and thermodiffusion coefficients of tetralin+isobutylbenzene+n-dodecane at a composition of (0.8/0.1/0.1) mass fractions by two-color optical beam deflection.

M Gebhardt1, W Köhler.   

Abstract

Within the framework of an international benchmark test we have performed measurements of the Soret and thermodiffusion coefficients of the organic ternary mixture (0.8/0.1/0.1 mass fraction) of 1,2,3,4-tetrahydronaphthaline (THN), isobutylbenzene (IBB) and n -dodecane (n C12) at 298.15K by means of a two-color optical beam deflection technique (OBD). The data evaluation procedure is based on a least squares fitting routine for an approximate analytical solution for the Soret cell problem. The condition number of the contrast factor matrix and standard error propagation are used for an error estimation for the measured Soret and thermodiffusion coefficients. The Soret coefficients obtained are S (') T(THN) = (1.20±0.09)×10(-3) K^-1, S (') T(IBB) = (- 0.34±0.14)×10(-3) K^-1, and S (') T(nC12) = (- 0.86±0.06)×10(-3) K^-1 and the corresponding thermodiffusion coefficients are D (') T(THN) = (0.72±0.26)×10(-12) m^2(s K)^-1, D (') T(IBB) = (- 0.22±0.42)×10(-12) m^2(s K)^-1, and D (') T(nC12) = (- 0.50±0.16)×10(-12) m^2(s K)^-1. These results will be used as ground-based reference data for the DCMIX project, where thermodiffusion experiments of ternary mixtures are measured in a microgravity environment aboard the International Space Station (ISS).

Entities:  

Year:  2015        PMID: 25904305     DOI: 10.1140/epje/i2015-15024-5

Source DB:  PubMed          Journal:  Eur Phys J E Soft Matter        ISSN: 1292-8941            Impact factor:   1.890


  6 in total

1.  Soret effect in interacting micellar solutions.

Authors:  Roberto Piazza; Andrea Guarino
Journal:  Phys Rev Lett       Date:  2002-05-02       Impact factor: 9.161

2.  Measurement of diffusion and thermal diffusion in ternary fluid mixtures using a two-color optical beam deflection technique.

Authors:  A Königer; H Wunderlich; W Köhler
Journal:  J Chem Phys       Date:  2010-05-07       Impact factor: 3.488

3.  On measurement of molecular and thermal diffusion coefficients in multicomponent mixtures.

Authors:  Kjetil B Haugen; Abbas Firoozabadi
Journal:  J Phys Chem B       Date:  2006-09-07       Impact factor: 2.991

4.  Measurement of the Soret and diffusion coefficients for benchmark binary mixtures by means of digital interferometry.

Authors:  A Mialdun; V Shevtsova
Journal:  J Chem Phys       Date:  2011-01-28       Impact factor: 3.488

5.  Development of a thermogravitational microcolumn with an interferometric contactless detection system.

Authors:  Philipp Naumann; Alain Martin; Hartmut Kriegs; Miren Larrañaga; M Mounir Bou-Ali; Simone Wiegand
Journal:  J Phys Chem B       Date:  2012-11-16       Impact factor: 2.991

6.  Diffusion, thermal diffusion, and Soret coefficients and optical contrast factors of the binary mixtures of dodecane, isobutylbenzene, and 1,2,3,4-tetrahydronaphthalene.

Authors:  M Gebhardt; W Köhler; A Mialdun; V Yasnou; V Shevtsova
Journal:  J Chem Phys       Date:  2013-03-21       Impact factor: 3.488

  6 in total
  2 in total

1.  Editorial: Thermal non-equilibrium phenomena in multi-component fluids.

Authors:  Fabrizio Croccolo; Henri Bataller
Journal:  Eur Phys J E Soft Matter       Date:  2015-04-29       Impact factor: 1.890

2.  The NEUF-DIX space project - Non-EquilibriUm Fluctuations during DIffusion in compleX liquids.

Authors:  Philipp Baaske; Henri Bataller; Marco Braibanti; Marina Carpineti; Roberto Cerbino; Fabrizio Croccolo; Aleksandar Donev; Werner Köhler; José M Ortiz de Zárate; Alberto Vailati
Journal:  Eur Phys J E Soft Matter       Date:  2016-12-12       Impact factor: 1.890

  2 in total

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