| Literature DB >> 25891069 |
Takenori Dairaku1, Kyoko Furuita, Hajime Sato, Jakub Šebera, Daichi Yamanaka, Hiroyuki Otaki, Shoko Kikkawa, Yoshinori Kondo, Ritsuko Katahira, F Matthias Bickelhaupt, Célia Fonseca Guerra, Akira Ono, Vladimír Sychrovský, Chojiro Kojima, Yoshiyuki Tanaka.
Abstract
We have observed the 1-bond (199)Hg-(15)N J-coupling ((1)J((199)Hg,(15)N) = 1050 Hz) within the Hg(II)-mediated thymine-thymine base pair (T-Hg(II)-T). This strikingly large (1)J((199)Hg,(15)N) is the first one for canonical sp(2)-nitrogen atoms, which can be a sensitive structure-probe of N-mercurated compounds and a direct evidence for N-mercuration.Entities:
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Year: 2015 PMID： 25891069 DOI： 10.1039/c5cc02423d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222