Literature DB >> 25884047

A novel carbamoyl radical based dearomatizing spiroacylation process.

Alejandra Millán-Ortiz1, German López-Valdez, Fernando Cortez-Guzmán, Luis D Miranda.   

Abstract

An easy access to novel spirodienonamides based on a dearomatizing spiroacylation process is described for the first time. This process was realized using carbamoylxanthates which were transformed into spirodienonamides containing an acyl-functionalized all-carbon quaternary center.

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Year:  2015        PMID: 25884047     DOI: 10.1039/c4cc06192f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Photochemical generation of acyl and carbamoyl radicals using a nucleophilic organic catalyst: applications and mechanism thereof.

Authors:  Eduardo de Pedro Beato; Daniele Mazzarella; Matteo Balletti; Paolo Melchiorre
Journal:  Chem Sci       Date:  2020-06-04       Impact factor: 9.825

  1 in total

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